Completely dissimilar: The reactivity of 1-unsubstituted 3-chloroquinoline-2,4-diones with ethylene diamine and ethanolamine to form new molecular rearrangements

Klásek, Antonín; Lyčka, Antonín; Rouchal, Michal

dc.title	Completely dissimilar: The reactivity of 1-unsubstituted 3-chloroquinoline-2,4-diones with ethylene diamine and ethanolamine to form new molecular rearrangements	en
dc.contributor.author	Klásek, Antonín
dc.contributor.author	Lyčka, Antonín
dc.contributor.author	Rouchal, Michal
dc.relation.ispartof	Arkivoc
dc.identifier.issn	1551-7004 Scopus Sources, Sherpa/RoMEO, JCR
dc.date.issued	2020
utb.relation.volume	2020
utb.relation.issue	6
dc.citation.spage	209
dc.citation.epage	219
dc.type	article
dc.language.iso	en
dc.publisher	Arkat
dc.identifier.doi	10.24820/ARK.5550190.P011.053dummy2
dc.relation.uri	https://www.arkat-usa.org/get-file/69213/
dc.subject	α-Aminoketones	en
dc.subject	indolones	en
dc.subject	quinazolinones	en
dc.subject	quinolinediones	en
dc.subject	rearrangement	en
dc.description.abstract	3-Chloroquinoline-2,4-diones react with ethanolamine to give 3-hydroxyethylaminoquinoline-2,4-diones. By reacting with isothiocyanic acid, these compounds cyclize to form thioxoimidazo derivatives. If a benzyl group is attached to carbon atom C-3, it is cleaved off. Simultaneously, molecular rearrangement proceeds through the formation of compounds with quinazoline skeletons. However, when using ethylene diamine, the compounds are subject to new types of molecular rearrangement leading to the formation of new quinazoline derivatives. © AUTHOR(S)	en
utb.faculty	Faculty of Technology
dc.identifier.uri	http://hdl.handle.net/10563/1009876
utb.identifier.obdid	43881662
utb.identifier.scopus	2-s2.0-85090146812
utb.identifier.wok	000584517600019
utb.identifier.coden	AGFUA
utb.source	j-scopus
dc.date.accessioned	2020-09-15T13:41:16Z
dc.date.available	2020-09-15T13:41:16Z
dc.description.sponsorship	TBU in Zlin [IGA/FT/2019/010]
dc.rights	Attribution 4.0 International
dc.rights.uri	https://creativecommons.org/licenses/by/4.0/
dc.rights.access	openAccess
utb.ou	Department of Chemistry
utb.contributor.internalauthor	Klásek, Antonín
utb.contributor.internalauthor	Rouchal, Michal
utb.fulltext.affiliation	Antonin Klásek a*, Antonin Lyčka b, Michal Rouchal a a Department of Chemistry, Faculty of Technology, Tomas Bata University, CZ-762 72 Zlín, Czech Republic b University of Hradec Králové, Faculty of Science, Rokitanského 62, CZ-500 03 Hradec Králové 3, Czech Republic E-mail: klasek@utb.cz
utb.fulltext.dates	-
utb.fulltext.sponsorship	A.K. and M.R. grateful for the financial support from the internal grant of TBU in Zlin No. IGA/FT/2019/010, funded from the resources of specific university research. The authors would also like to thank Mrs. H. Geržová (Faculty of Technology, Tomas Bata University in Zlín) for her technical assistance.
utb.wos.affiliation	[Klasek, Antonin; Rouchal, Michal] Tomas Bata Univ, Fac Technol, Dept Chem, CZ-76272 Zlin, Czech Republic; [Lycka, Antonin] Univ Hradec Kralove, Fac Sci, Rokitanskeho 62, CZ-50003 Hradec Kralove 3, Czech Republic
utb.scopus.affiliation	Department of Chemistry, Faculty of Technology, Tomas Bata University, Zlín, CZ-762 72, Czech Republic; University of Hradec Králové, Faculty of Science, Rokitanského 62, Hradec Králové 3, CZ-500 03, Czech Republic
utb.fulltext.projects	IGA/FT/2019/010
utb.fulltext.faculty	Faculty of Technology
utb.fulltext.faculty	Faculty of Technology
utb.fulltext.ou	Department of Chemistry
utb.fulltext.ou	Department of Chemistry