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Adamantylated trisimidazolium-based tritopic guests and their binding properties towards cucurbit[7]uril and beta-cyclodextrin

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dc.title Adamantylated trisimidazolium-based tritopic guests and their binding properties towards cucurbit[7]uril and beta-cyclodextrin en
dc.contributor.author Kulkarni, Shantanu Ganesh
dc.contributor.author Prucková, Zdeňka
dc.contributor.author Rouchal, Michal
dc.contributor.author Dastychová, Lenka
dc.contributor.author Vícha, Robert
dc.relation.ispartof Journal of Inclusion Phenomena and Macrocyclic Chemistry
dc.identifier.issn 0923-0750 Scopus Sources, Sherpa/RoMEO, JCR
dc.date.issued 2016
utb.relation.volume 84
utb.relation.issue 1-2
dc.citation.spage 11
dc.citation.epage 20
dc.type article
dc.language.iso en
dc.publisher Springer
dc.identifier.doi 10.1007/s10847-015-0577-9
dc.relation.uri https://link.springer.com/article/10.1007/s10847-015-0577-9
dc.subject Adamantane en
dc.subject Multitopic guests en
dc.subject Imidazolium salts en
dc.subject Binding properties en
dc.subject Host-guest systems en
dc.description.abstract Two new homotritopic guests based on tris(benz) imidazolium salts with adamantane binding sites were prepared. NMR and calorimetric titration experiments revealed that each of the three sites independently binds beta-cyclodextrin (beta-CD) or cucurbit[7]uril (CB7) units to form binary host-guest complexes with 1:3 stoichiometry. The association constants for the single binding site for beta-CD and CB7 were determined using titration calorimetry and are in the order of 10(5) and 10(9-10) dm(3) mol(-1), respectively. In addition, both guests were able to form ternary systems with beta-CD and CB7 in ratios of 1:1:2 and 1:2:1, respectively. en
utb.faculty Faculty of Technology
dc.identifier.uri http://hdl.handle.net/10563/1006341
utb.identifier.obdid 43875134
utb.identifier.scopus 2-s2.0-84979233563
utb.identifier.wok 000371794400002
utb.identifier.coden JIMCE
utb.source j-wok
dc.date.accessioned 2016-06-22T12:14:49Z
dc.date.available 2016-06-22T12:14:49Z
dc.description.sponsorship Internal Funding Agency of the Tomas Bata University in Zlin [IGA/FT/2015/005]
utb.contributor.internalauthor Kulkarni, Shantanu Ganesh
utb.contributor.internalauthor Prucková, Zdeňka
utb.contributor.internalauthor Rouchal, Michal
utb.contributor.internalauthor Dastychová, Lenka
utb.contributor.internalauthor Vícha, Robert
utb.fulltext.affiliation Shantanu Ganesh Kulkarni 1, Zdeňka Prucková 1, Michal Rouchal 1, Lenka Dastychová 1, Robert Vícha 1 1 Department of Chemistry, Faculty of Technology, Tomas Bata University in Zlín, Vavrečkova 275, 760 01 Zlín, Czech Republic Robert Vícha rvicha@ft.utb.cz
utb.fulltext.dates Received: 24 September 2015 Accepted: 26 October 2015 Published online: 3 November 2015
utb.fulltext.faculty Faculty of Technology
utb.fulltext.faculty Faculty of Technology
utb.fulltext.faculty Faculty of Technology
utb.fulltext.faculty Faculty of Technology
utb.fulltext.faculty Faculty of Technology
utb.fulltext.ou Department of Chemistry
utb.fulltext.ou Department of Chemistry
utb.fulltext.ou Department of Chemistry
utb.fulltext.ou Department of Chemistry
utb.fulltext.ou Department of Chemistry
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