Preparation of 1-adamantyl ketones: Structure, mechanism of formation and biological activity of potential by-products

Vícha, Robert; Nečas, Marek; Potáček, Milan

Title:

Author:

Vícha, Robert; Nečas, Marek; Potáček, Milan

Document type:

Peer-reviewed article (English)

Source document:

Collection of Czechoslovak Chemical Communications. 2006, vol. 71, issue 5, p. 709-722

ISSN:

0010-0765 (Sherpa/RoMEO, JCR)

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DOI:

https://doi.org/10.1135/cccc20060709

Abstract:

Reactions between adamantane-1-carbonyl chloride and several Grignard reagents as well as interactions with solvents have been examined. Some new and unexpected adamantane derivatives were isolated, fully characterized and their biological activity determined. In particular, an unexpected isochromanone 16 was formed in an SEAr process, in which a stable hydrocarbon was the leaving group.

Full text:

http://cccc.uochb.cas.cz/71/5/0709/

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Citace článku v časopise:
VÍCHA, Robert, Marek NEČAS a Milan POTÁČEK. Preparation of 1-adamantyl ketones: Structure, mechanism of formation and biological activity of potential by-products. Collection of Czechoslovak Chemical Communications [online]. 2006, vol. 71, iss. 5, s. 709-722. [cit. 2024-04-19]. ISSN 0010-0765. Dostupné z: http://cccc.uochb.cas.cz/71/5/0709/.

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