Quantification of shape parameters of Co-Cr-Mo-Si multiphase compounds and their role in the processing of metal injection molding feedstocks

Abstract

Particle shape is one of the most important powder attributes affecting the properties of multiphase compounds intended for metal injection molding. This work reports the processability of gas (GA) and water (WA) atomized Co-Cr-Mo-Si alloy related to quantitative analyses of particle shape using a newly developed algorithm based on the Euclidean distance mapping, which results are compared with those of commercially available dynamic image analysis. Both methods reveal similar values for the parameters that quantify the shape of the powders, such as circularity, aspect ratio, and symmetry. The alloys were mixed with wax/high-density polyethylene (50/50 wt%) binder using a double sigma mixer to produce homogeneous feedstocks. The critical solid loading and flow performance corresponding to the differences in powder shapes were derived from the torque and capillary rheometers, respectively, to obtain the optimum molding parameters. A stable and repeatable viscosity was observed for the GA feedstock, whereas the compound containing WA was prone to phase separation during flow. The defect-free sintered specimens were examined by metallographic analysis; the GA powder compound could be sintered to a maximum of 99.2 % of the theoretical density, whereas the irregular WA powder reached a maximum of 98.8 % of the theoretical density, and the carbon residue was found to be higher for the GA feedstock. The GA samples had a significantly higher ultimate tensile strength owing to their larger symmetry, which resulted in a lower porosity and stress concentration.