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Imprinting of different types of graphene oxide with metal cations

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dc.title Imprinting of different types of graphene oxide with metal cations en
dc.contributor.author Zabierowski, Piotr Wladyslaw
dc.contributor.author Osička, Josef
dc.contributor.author Šťastný, Josef
dc.contributor.author Filip, Jaroslav
dc.relation.ispartof Electrochimica Acta
dc.identifier.issn 0013-4686 Scopus Sources, Sherpa/RoMEO, JCR
dc.identifier.issn 1873-3859 Scopus Sources, Sherpa/RoMEO, JCR
dc.date.issued 2022
utb.relation.volume 434
dc.type article
dc.language.iso en
dc.publisher Pergamon-Elsevier Science Ltd
dc.identifier.doi 10.1016/j.electacta.2022.141307
dc.relation.uri https://www.sciencedirect.com/science/article/pii/S0013468622014645
dc.relation.uri https://www.sciencedirect.com/science/article/pii/S0013468622014645/pdfft?md5=e9f0e3f3f56b0c87fed7da2b9f6b14dd&pid=1-s2.0-S0013468622014645-main.pdf
dc.subject graphene oxide en
dc.subject metal cations en
dc.subject electrochemical determination en
dc.subject toxic metals en
dc.subject ion imprinting en
dc.description.abstract It is known that graphene oxide (GO) particles bear negatively charged oxygen moieties which can interact with cations, what has been several times employed in fabrication of electrochemical sensors for metals. In this work, for the first time GO was treated with Cu2+, Cd2+ or Pb2+ cations in a way similar to the ion imprinting by simple incubation of the two components and the synthesized nanomaterials were then deposited on carbon electrode surface forming electrochemical sensors towards lead cations. It was found that simple filtration of GO is very efficient way for collection of GO particles that could be imprinted most efficiently in terms of high electrochemical response towards lead cations. Part of the success also lies in high redox potential of Cu2+ that turned to be the best choice for the GO imprinting. It was also proven that the electrodes modified with ion-imprinted GO could work as the sensors of Pb2+ in drop amount of solution as well as they provide stable response under flowthrough cell conditions suitable, for example, for online monitoring of water quality. en
utb.faculty Faculty of Technology
utb.faculty University Institute
dc.identifier.uri http://hdl.handle.net/10563/1011182
utb.identifier.obdid 43883974
utb.identifier.scopus 2-s2.0-85139876760
utb.identifier.wok 000930651800007
utb.identifier.coden ELCAA
utb.source j-scopus
dc.date.accessioned 2022-10-26T13:40:45Z
dc.date.available 2022-10-26T13:40:45Z
dc.description.sponsorship Grantová Agentura České Republiky, GA ČR: GAČR 20–27735Y
dc.description.sponsorship Czech science foundation [GA.CR 20-27735Y]
dc.description.sponsorship Czech science foundation [GAC ?, R 20 - 27735Y]
utb.ou Department of Environmental Protection Engineering
utb.ou Centre of Polymer Systems
utb.contributor.internalauthor Zabierowski, Piotr Wladyslaw
utb.contributor.internalauthor Osička, Josef
utb.contributor.internalauthor Šťastný, Josef
utb.contributor.internalauthor Filip, Jaroslav
utb.fulltext.affiliation Piotr Zabierowski a,b, Josef Osička c, Josef Šťastný a, Jaroslav Filip a,* a Department of Environmental Protection Engineering, Faculty of Technology, Tomas Bata University in Zlin, Nad Ovcirnou 3685, Zlin 760 01, Czech Republic b CNR – Istituto per i Processi Chimico-Fisici, Sezione di Bari, via E. Orabona, 4, Bari 70126, Italy c Centre of Polymer Systems, Tomas Bata University in Zlin, Trida Tomase Bati 5678, Zlin 760 01, Czech Republic * Corresponding author. E-mail address: jfilip@utb.cz (J. Filip).
utb.fulltext.dates Received 9 August 2022 Received in revised form 3 October 2022 Accepted 5 October 2022 Available online 6 October 2022
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utb.fulltext.sponsorship This work was supported by Czech science foundation [grant number GAČR 20–27735Y].
utb.wos.affiliation [Zabierowski, Piotr; Stastny, Josef; Filip, Jaroslav] Tomas Bata Univ Zlin, Fac Technol, Dept Environm Protect Engn, Nad Ovcirnou 3685, Zlin 76001, Czech Republic; [Zabierowski, Piotr] CNR, Sez Bari, Ist Proc Chim Fis, Via E Orabona 4, I-70126 Bari, Italy; [Osicka, Josef] Tomas Bata Univ Zlin, Ctr Polymer Syst, Trida Tomase Bati 5678, Zlin 76001, Czech Republic
utb.scopus.affiliation Department of Environmental Protection Engineering, Faculty of Technology, Tomas Bata University in Zlin, Nad Ovcirnou 3685, Zlin, 760 01, Czech Republic; CNR – Istituto per i Processi Chimico-Fisici, Sezione di Bari, via E. Orabona, 4, Bari, 70126, Italy; Centre of Polymer Systems, Tomas Bata University in Zlin, Trida Tomase Bati 5678, Zlin, 760 01, Czech Republic
utb.fulltext.projects GAČR 20–27735Y
utb.fulltext.faculty Faculty of Technology
utb.fulltext.ou Department of Environmental Protection Engineering
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