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Influence of clay nanofillers on properties of ethylene-octene copolymers

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dc.title Influence of clay nanofillers on properties of ethylene-octene copolymers en
dc.contributor.author Tesaříková, Alice
dc.contributor.author Měřínská, Dagmar
dc.contributor.author Kalous, Jiří
dc.contributor.author Svoboda (FT), Petr
dc.relation.ispartof Polymer Composites
dc.identifier.issn 0272-8397 Scopus Sources, Sherpa/RoMEO, JCR
dc.date.issued 2017
dc.type article
dc.language.iso en
dc.publisher John Wiley and Sons Inc.
dc.identifier.doi 10.1002/pc.24568
dc.relation.uri https://onlinelibrary.wiley.com/doi/abs/10.1002/pc.24568
dc.description.abstract The article deals with preparation, properties and usage of ethylene-octene copolymers/clay films. Different properties of two types of ethylene-octene copolymers (Engage 8540 and Engage 8842) with 17 and 45 wt% of octene (EOC-17 and EOC-45) were compared in nanocomposites with two types of clays-Cloisite 93A and Dellite 67. The aim was to evaluate the influence of (nano)filler type on ethylene-octene nanocomposites properties. Mechanical and thermal properties, morphology, and UV radiation degradation were observed. Furthermore, permeability of three different gasses was determined. EOC nanocomposites perform a higher elongation at break, especially EOC-45. Dynamic Mechanical Analysis (DMA) showed an increase of E' modulus of all nanocomposites in a wide range of temperatures compared to pure EOC. Intercalation of nanofillers was studied by transmission electron microscopy (TEM) and X-ray diffraction (XRD). It has been proved that EOC-45 has a better dispersion EOC-17. DSC analysis showed a shift in a crystallization temperature for EOC-17, where the nanofiller acted as a nucleation agent due to the worse dispersion. Barrier properties were improved by almost 100% by addition of organoclay for all measured gasses; they were best for EOC-17 nanocomposites due to a higher crystallinity. XRD together with transmission electron microscopy (TEM) showed much better dispersion for EOC-45 nanocomposites. Fourier transform infrared spectroscopy (FTIR) and accelerated UV aging showed C=O peaks for EOC nanocomposites. © 2017 Society of Plastics Engineers. en
utb.faculty Faculty of Technology
dc.identifier.uri http://hdl.handle.net/10563/1007868
utb.identifier.obdid 43878930
utb.identifier.scopus 2-s2.0-85030157720
utb.identifier.wok 000454635300032
utb.identifier.coden PCOMD
utb.source j-scopus
dc.date.accessioned 2018-04-23T15:01:49Z
dc.date.available 2018-04-23T15:01:49Z
dc.description.sponsorship TBU in Zlin [TA03010799, FR-TI 4/623, IGA/FT/2017/007]
utb.contributor.internalauthor Tesaříková, Alice
utb.contributor.internalauthor Měřínská, Dagmar
utb.contributor.internalauthor Kalous, Jiří
utb.contributor.internalauthor Svoboda (FT), Petr
utb.fulltext.affiliation Alice Tesarikova , Dagmar Merinska, Jiri Kalous, Petr Svoboda Department of Polymer Engineering, Faculty of Technology, Tomas, Bata University in Zlin, Vavreckova 275, Zlin, Czech Republic 762 72 Correspondence to: A. Tesarikova; e-mail: atesarikova@ft.utb.cz or D. Merinska; e-mail: merinska@ft.utb.cz
utb.fulltext.dates -
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utb.fulltext.sponsorship This article was written with the support of the project TA03010799, FR-TI 4/623, and IGA/FT/2017/007 TBU in Zlin.
utb.scopus.affiliation Department of Polymer Engineering, Faculty of TechnologyTomas, Bata University in Zlin, Vavreckova 275Zlin 762 72Czech Republic
utb.fulltext.projects TA03010799
utb.fulltext.projects FR-TI 4/623
utb.fulltext.projects IGA/FT/2017/007
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