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Modulation of wettability, gradient and adhesion on self-assembled monolayer by counterion exchange and pH

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dc.title Modulation of wettability, gradient and adhesion on self-assembled monolayer by counterion exchange and pH en
dc.contributor.author Mosnáček, Jaroslav
dc.contributor.author Popelka, Anton
dc.contributor.author Osička, Josef
dc.contributor.author Filip, Jaroslav
dc.contributor.author Ilčíková, Monika
dc.contributor.author Kollár, Jozef
dc.contributor.author Yousaf, Ammar B.
dc.contributor.author Bertók, Tomáš
dc.contributor.author Tkáč, Jan
dc.contributor.author Kasák, Peter
dc.relation.ispartof Journal of Colloid and Interface Science
dc.identifier.issn 0021-9797 Scopus Sources, Sherpa/RoMEO, JCR
dc.date.issued 2018
utb.relation.volume 512
dc.citation.spage 511
dc.citation.epage 521
dc.type article
dc.language.iso en
dc.publisher Academic Press Ltd.Elsevier Science Ltd.
dc.identifier.doi 10.1016/j.jcis.2017.10.086
dc.relation.uri https://www.sciencedirect.com/science/article/pii/S0021979717312559
dc.subject Adsorption en
dc.subject Counterion exchange en
dc.subject Self-assembled monolayer en
dc.subject Superwettability en
dc.subject Wettability gradient en
dc.description.abstract In this study, two quaternary ammonium salts derived from L-lipoic acid were applied for self-assembled monolayers formation on rough structured gold surface. The derivatives differ in functionality since one possesses simple quaternary ammonium group whereas the other one is carboxybetaine ester containing quaternary ammonium group with pH hydrolysable ester group as a pendant. The response of surface wettability to ion exchange between Cl− and perfluorooctanoate, kinetics and gradient wettability were examined by water contact angle measurement and confirmed by X-ray photoelectron spectroscopy. Furthermore, adhesion forces related to applied counterion on the entire surface and after hydrolysis were investigated by atomic force microscopy measurement at nanometer scales. A dramatic change in wettability upon counterion exchange from superhydrophilic for Cl− to very or superhydrophobic for perfluorooctanoate in a repeatable manner was observed for both derivatives. Kinetics of counterion exchanges revealed faster hydration of simple quaternary derivate. The wettability gradient could be designed from superhydrophobic to superhydrophilic either in a reversible manner by simple immersion of the modified surface in a counterion solution modulated by ionic strength or in an irreversible manner for carboxybetaine ester derivate by time-controlled hydrolysis to charge balanced carboxybetaine. © 2017 Elsevier Inc. en
utb.faculty Faculty of Technology
dc.identifier.uri http://hdl.handle.net/10563/1007570
utb.identifier.obdid 43878224
utb.identifier.scopus 2-s2.0-85032382013
utb.identifier.wok 000418729500057
utb.identifier.pubmed 29096112
utb.identifier.coden JCISA
utb.source j-scopus
dc.date.accessioned 2018-01-15T16:31:29Z
dc.date.available 2018-01-15T16:31:29Z
dc.description.sponsorship QUUG-CAM-2017-1, QU, Qatar University
dc.description.sponsorship Qatar University [QUUG-CAM-2017-1]; NPRP grant from the Qatar National Research Fund (Qatar Foundation) [NPRP-6-381-1-078, NPRP-9-219-2-105]
utb.contributor.internalauthor Filip, Jaroslav
utb.fulltext.affiliation Jaroslav Mosnáček a,b , Anton Popelka a , Josef Osicka a , Jaroslav Filip c , Marketa Ilcikova a,b , Jozef Kollar a,b , Ammar B. Yousaf a , Tomas Bertok d , Jan Tkac d , Peter Kasak a, ⇑ a Center for Advanced Materials, Qatar University, P.O. Box 2713, Doha, Qatar b Polymer Institute, Slovak Academy of Sciences, Dubravska cesta 9, 845 41 Bratislava, Slovak Republic c Department of Environment Protection Engineering, Tomas Bata University, Vavreckova 275, 760 01 Zlin, Czech Republic d Department of Glycobiotechnology, Institute of Chemistry, Slovak Academy of Sciences, Dubravská cesta 9, 845 38 Bratislava, Slovak Republic ⇑ Corresponding author. E-mail address: peter.kasak@qu.edu.qa (P. Kasak).
utb.fulltext.dates Received 13 September 2017 Revised 18 October 2017 Accepted 23 October 2017 Available online 25 October 2017
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utb.fulltext.sponsorship The authors gratefully acknowledge Mr Ahmed Suliman, Gas Processing Center Qatar University, for carrying out the XPS analysis. This publication was supported by Qatar University Grant QUUG-CAM-2017-1. This publication was made possible by NPRP grant # NPRP-6-381-1-078 and NPRP-9-219-2-105 from the Qatar National Research Fund (member of Qatar Foundation). The statements made herein are solely the responsibility of the authors.
utb.scopus.affiliation Center for Advanced Materials, Qatar University, P.O. Box 2713, Doha, Qatar; Polymer Institute, Slovak Academy of Sciences, Dubravska cesta 9, Bratislava, Slovakia; Department of Environment Protection Engineering, Tomas Bata University, Vavreckova 275, Zlin, Czech Republic; Department of Glycobiotechnology, Institute of Chemistry, Slovak Academy of Sciences, Dubravská cesta 9, Bratislava, Slovakia
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