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Cubane arrives on the cucurbituril scene

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dc.title Cubane arrives on the cucurbituril scene en
dc.contributor.author Jelínková, Kristýna
dc.contributor.author Surmová, Heda
dc.contributor.author Matelová, Alena
dc.contributor.author Rouchal, Michal
dc.contributor.author Prucková, Zdeňka
dc.contributor.author Dastychová, Lenka
dc.contributor.author Nečas, Marek
dc.contributor.author Vícha, Robert
dc.relation.ispartof Organic Letters
dc.identifier.issn 1523-7060 Scopus Sources, Sherpa/RoMEO, JCR
dc.date.issued 2017
utb.relation.volume 19
utb.relation.issue 10
dc.citation.spage 2698
dc.citation.epage 2701
dc.type article
dc.language.iso en
dc.publisher American Chemical Society (ACS)
dc.identifier.doi 10.1021/acs.orglett.7b01029
dc.relation.uri http://pubs.acs.org/doi/abs/10.1021/acs.orglett.7b01029
dc.description.abstract Cubane, an intriguing chemical curiosity first studied in the early 1960s, has become a valuable structural motif and has recently been involved in the structures of a great number of prospective compounds. The first dicationic supramolecular guest 5 is prepared and derived from a 1,4-disubstituted cubane moiety, and its binding behavior toward cucurbit[n]urils (CBn) and cyclodextrins (CD) is studied. The bisimidazolium salt 5 forms 1:1 inclusion complexes with CB7, CB8, and β-CD with the respective association constants (6.7 ± 0.5) × 1011 M-1, (1.5 ± 0.2) × 109 M-1, and <102 M-1 in water. The solid-state structures of the 5@CB7 and 5@CB8 complexes are also reported. © 2017 American Chemical Society. en
utb.faculty Faculty of Technology
dc.identifier.uri http://hdl.handle.net/10563/1007356
utb.identifier.obdid 43876690
utb.identifier.scopus 2-s2.0-85019387070
utb.identifier.wok 000402023500061
utb.identifier.pubmed 28467704
utb.identifier.coden ORLEF
utb.source j-scopus
dc.date.accessioned 2017-09-08T12:14:44Z
dc.date.available 2017-09-08T12:14:44Z
dc.description.sponsorship Internal Founding Agency of Tomas Bata University in Zlin [IGA/FT/2017/001]; MEYS CR [LM2015043]
utb.contributor.internalauthor Jelínková, Kristýna
utb.contributor.internalauthor Surmová, Heda
utb.contributor.internalauthor Matelová, Alena
utb.contributor.internalauthor Rouchal, Michal
utb.contributor.internalauthor Prucková, Zdeňka
utb.contributor.internalauthor Dastychová, Lenka
utb.contributor.internalauthor Vícha, Robert
utb.fulltext.affiliation Kristýna Jelínková †, Heda Surmová †, Alena Matelová †, Michal Rouchal †, Zdeňka Prucková †, Lenka Dastychová †, Marek Nečas ‡, Robert Vícha *† † Department of Chemistry, Faculty of Technology, Tomas Bata University in Zlín, Vavreckova 275, 760 01 Zlín, Czech Republic ‡ Department of Chemistry, Faculty of Science, Masaryk University, Kamenice 5, 625 00 Brno, Czech Republic
utb.fulltext.dates Received: April 5, 2017 Published: May 3, 2017
utb.fulltext.faculty Faculty of Technology
utb.fulltext.faculty Faculty of Technology
utb.fulltext.faculty Faculty of Technology
utb.fulltext.faculty Faculty of Technology
utb.fulltext.faculty Faculty of Technology
utb.fulltext.faculty Faculty of Technology
utb.fulltext.faculty Faculty of Technology
utb.fulltext.ou Department of Chemistry
utb.fulltext.ou Department of Chemistry
utb.fulltext.ou Department of Chemistry
utb.fulltext.ou Department of Chemistry
utb.fulltext.ou Department of Chemistry
utb.fulltext.ou Department of Chemistry
utb.fulltext.ou Department of Chemistry
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