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Electrical transport properties of poly(aniline-co-p-phenylenediamine) and its composites with incorporated silver particles

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dc.title Electrical transport properties of poly(aniline-co-p-phenylenediamine) and its composites with incorporated silver particles en
dc.contributor.author Moučka, Robert
dc.contributor.author Mrlík, Miroslav
dc.contributor.author Ilčíková, Markéta
dc.contributor.author Spitalsky, Zdenko
dc.contributor.author Kazantseva, Natalia E.
dc.contributor.author Bober, Patrycja
dc.contributor.author Stejskal, Jaroslav
dc.relation.ispartof Chemical Papers
dc.identifier.issn 0366-6352 Scopus Sources, Sherpa/RoMEO, JCR
dc.date.issued 2013
utb.relation.volume 67
utb.relation.issue 8
dc.citation.spage 1012
dc.citation.epage 1019
dc.type article
dc.language.iso en
dc.publisher Versita en
dc.identifier.doi 10.2478/s11696-013-0351-7
dc.relation.uri https://link.springer.com/article/10.2478/s11696-013-0351-7
dc.subject polyaniline en
dc.subject p-phenylenediamine en
dc.subject poly(p-phenylenediamine) en
dc.subject copolymer en
dc.subject silver particles en
dc.subject dielectric properties en
dc.subject conductivity en
dc.description.abstract Statistical copolymers of aniline and p-phenylenediamine, poly(aniline-co-p-phenylenediamine)s, were synthesised by oxidative polymerisation using various oxidants, ammonium peroxydisulphate or silver nitrate. Depending on the choice of oxidant, copolymers or composites with silver particles were obtained. Different molar concentrations of p-phenylenediamine in the reaction mixture provided materials of different conductivities. The influence of both the copolymer composition and the presence of discrete silver particles on the electric and dielectric properties of the system was studied. The results showed a decrease in the conductivity of copolymers and their composites with the silver content compared with the content of standard polyaniline salt. The reduction in conductivity was described in terms of the decreased density of hopping centres due to defects in the copolymer structure. The dielectric relaxations observed were described in terms of their activation energies and were linked to the corresponding conduction mechanism. en
utb.faculty Faculty of Technology
dc.identifier.uri http://hdl.handle.net/10563/1003271
utb.identifier.obdid 43869829
utb.identifier.scopus 2-s2.0-84879422760
utb.identifier.wok 000318443700019
utb.identifier.coden CHPAE
utb.source j-wok
dc.date.accessioned 2013-07-27T14:54:38Z
dc.date.available 2013-07-27T14:54:38Z
utb.contributor.internalauthor Moučka, Robert
utb.contributor.internalauthor Mrlík, Miroslav
utb.contributor.internalauthor Kazantseva, Natalia E.
utb.fulltext.affiliation a,bRobert Moucka*, a,bMiroslav Mrlik, c Marketa Ilcikova, dZdenko Spitalsky, a,bNatalia Kazantseva, ePatrycja Bober, e Jaroslav Stejskal a Centre for Polymer Systems, University Institute, Tomáš Baťa University in Zlín, Nad Ovčírnou 3685, 760 01 Zlín, Czech Republic b Polymer Centre, Faculty of Technology, Tomáš Baťa University in Zlín, T. G. Masaryk Sq. 275, 762 72 Zlín, Czech Republic c Centre of Excellence SAS for Functionalized Multiphase Materials (FUN-MAT), Polymer Institute, Slovak Academy of Sciences, Dúbravská cesta 9, 845 41 Bratislava, Slovakia d Polymer Institute, Slovak Academy of Sciences, Dúbravská cesta 9, 845 41 Bratislava, Slovakia e Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, Heyrovský Sq. 2, 162 06 Prague 6, Czech Republic
utb.fulltext.dates Received 20 August 2012 Revised 17 December 2012 Accepted 18 December 2012
utb.fulltext.sponsorship This work was performed with the financial support of a bilateral Czech and Slovak project (7AMB12SK113 and SK-CZ-0174-11. respectively) co-funded by the Ministry of Education, Youth and Sports of the Czech Republic and the Slovak Research and Development Agency. The authors also wish to acknowledge the financial support received from the Operational Programme: Research and Development for Innovations co-funded by the European Regional Development Fund (ERDF) and the national budget of the Czech Republic, within the framework of the project of the Centre of Polymer Systems (CZ.1.05/2.1.00/03.0111) and of the Czech Grant Agency (202/09/1626) as well as Operational Program Education for Competitiveness co-funded by the European Social Fund (ESF) and national budget of Czech Republic, within the framework of project Advanced Theoretical and Experimental Studies of Polymer Systems (reg. number:CZ.1.07/2.3.00/20.0104).
utb.fulltext.faculty University Institute
utb.fulltext.faculty Faculty of Technology
utb.fulltext.ou Centre for Polymer Systems
utb.fulltext.ou Polymer Centre
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