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Novel adamantane-bearing anilines and properties of their supramolecular complexes with β-cyclodextrin

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dc.title Novel adamantane-bearing anilines and properties of their supramolecular complexes with β-cyclodextrin en
dc.contributor.author Vícha, Robert
dc.contributor.author Rouchal, Michal
dc.contributor.author Kozubková, Zuzana
dc.contributor.author Kuřitka, Ivo
dc.contributor.author Marek, Radek
dc.contributor.author Branná, Petra
dc.contributor.author Čmelík, Richard
dc.relation.ispartof Supramolecular Chemistry
dc.identifier.issn 1061-0278 Scopus Sources, Sherpa/RoMEO, JCR
dc.date.issued 2011
utb.relation.volume 23
utb.relation.issue 10
dc.citation.spage 663
dc.citation.epage 677
dc.type article
dc.language.iso en
dc.publisher Taylor and Francis en
dc.identifier.doi 10.1080/10610278.2011.593628
dc.relation.uri http://www.tandfonline.com/doi/abs/10.1080/10610278.2011.593628
dc.subject Adamantane en
dc.subject Amines en
dc.subject Cyclodextrins en
dc.subject Host-guest systems en
dc.description.abstract Several novel anilines bearing 1-adamantyl substituents that are useful for drug modification were synthesised from the corresponding 1-adamantyl (nitrophenyl) ketones. The host-guest systems of these prepared ligands with β-cyclodextrin (β-CD) were studied using electrospray ionisation mass spectrometry, NMR spectroscopy, titration calorimetry and semiempirical calculations. The complexes with 1:1 stoichiometry were found to predominantly exist as pseudorotaxane-like threaded structures with the adamantane cage sitting deep in the cavity of β-CD close to the wider rim. Such geometry was observed for all examined amines and is independent of their structure and/or presence of protic substituents. © 2011 Taylor & Francis. en
utb.faculty Faculty of Technology
dc.identifier.uri http://hdl.handle.net/10563/1002728
utb.identifier.rivid RIV/70883521:28110/11:43866560!RIV12-MSM-28110___
utb.identifier.obdid 43866681
utb.identifier.scopus 2-s2.0-84855812114
utb.identifier.wok 000299563700001
utb.source j-scopus
dc.date.accessioned 2012-02-20T09:34:25Z
dc.date.available 2012-02-20T09:34:25Z
utb.contributor.internalauthor Vícha, Robert
utb.contributor.internalauthor Rouchal, Michal
utb.contributor.internalauthor Kozubková, Zuzana
utb.contributor.internalauthor Kuřitka, Ivo
utb.contributor.internalauthor Branná, Petra
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