A novel approach for qualitative determination of residual tin based catalyst in poly(lactic acid) by X-ray photoelectron spetroscopy

Sedlařík, Vladimír; Vesel, Alenka; Kucharczyk, Pavel; Urbánek, Pavel

dc.title	A novel approach for qualitative determination of residual tin based catalyst in poly(lactic acid) by X-ray photoelectron spetroscopy	en
dc.contributor.author	Sedlařík, Vladimír
dc.contributor.author	Vesel, Alenka
dc.contributor.author	Kucharczyk, Pavel
dc.contributor.author	Urbánek, Pavel
dc.relation.ispartof	Materiali in Tehnologije
dc.identifier.issn	1580-2949 Scopus Sources, Sherpa/RoMEO, JCR
dc.date.issued	2011
utb.relation.volume	45
utb.relation.issue	3
dc.citation.spage	213
dc.citation.epage	216
dc.type	article
dc.language.iso	en
dc.publisher	Institut za Kovinske Materiale in Tehnologije Ljubljana	sl
dc.relation.uri	http://mit.imt.si/Revija/mit113.html
dc.subject	poly(lactic acid)	en
dc.subject	catalyst residuals	en
dc.subject	tin	en
dc.subject	X-ray photoelectron spectroscopy	en
dc.subject	fluorimetry	en
dc.description.abstract	This work is focused on description of qualitative determination of residual tin based catalysts in poly(lactic acid) by using X-ray photoelectron spectroscopy and fluorimetry as standard technique. Three types of poly(lactic acid) were prepared by direct melt polycondensation of lactic acid by using methanesulfonic acid (w = 0.5 %) or various amount of stannous 2-ethylhexanoate (w = (0.5 and 2) %). The results from both methods show that the amount of observed tin in the samples correlates with the concentration of the stannous 2-ethylhexanoate used for polycondensation. X-ray photoelectron spectroscopy was proven to be suitable for detection of tin residuals in polymer matrix.	en
utb.faculty	Faculty of Technology
utb.faculty	University Institute
dc.identifier.uri	http://hdl.handle.net/10563/1002189
utb.identifier.rivid	RIV/70883521:28110/11:43865320!RIV12-MSM-28110___
utb.identifier.rivid	RIV/70883521:28610/11:43865320!RIV12-MSM-28610___
utb.identifier.obdid	43865322
utb.identifier.scopus	2-s2.0-79957984262
utb.identifier.wok	000291170700008
utb.source	j-wok
dc.date.accessioned	2011-08-16T15:06:38Z
dc.date.available	2011-08-16T15:06:38Z
dc.rights.uri	http://mit.imt.si/
dc.rights.access	openAccess
utb.ou	Centre of Polymer Systems
utb.contributor.internalauthor	Sedlařík, Vladimír
utb.contributor.internalauthor	Kucharczyk, Pavel
utb.contributor.internalauthor	Urbánek, Pavel
utb.fulltext.affiliation	Vladimír Sedlařík1,3*, Alenka Vesel2, Pavel Kucharczyk3, Pavel Urbánek3 1 Jožef Stefan Institute, Jamova cesta 39, 1000 Ljubljana, Slovenia 2 Center of Excellence for Polymer Materials and Technologies, Tehnološki park 24, 1000 Ljubljana, Slovenia 3 Centre of Polymer Systems, Polymer Centre, Tomas Bata University in Zlín, nám. T. G. Masaryka 5555, 760 01 Zlín, Czech Republic sedlarik@ft.utb.cz
utb.fulltext.dates	Prejem rokopisa – received: 2011-02-15 sprejem za objavo – accepted for publication: 2011-03-04
utb.fulltext.references	1 Y. Wan, C. Tu, J. Yang, J. Bei, S Wang, Biomaterials, 27 (2006), 2699–2704 2 L. Safinia, K. Wilson, A. Mantalaris, A. Bismarck, J. Biomed. Mater. Res. A, 87A (2008) 3, 632–642 3 D. Cam, M. Marucci, Polymer, 38 (1997) 8, 1879–1884 4 M. Gricar, I. Poljansek, B. Brulc, T. Smigovec, M. Zidon, E. Zagar, Acta. Chim. Slov., 55 (2008) 3, 575–581 5 I. Poljansek, M. Gricar, E. Zagar, M. Zigon, Macromolecular Symposia, 272 (2008), 75–80 6 M. Vukomanovic, S. D. Skapin, I. Poljansek, E. Zagar, B. Kralj, N. Ignjatovic, D. Uskokovic, Colloids. Surf., B Biointerfaces., 82 (2011) 2, 414–421 7 C.M. Alves et al., J. Biomed. Res. B, 87B (2008) 1, 59–66 8 T. A. P. Engels, S. H. M. Sontjens, T. H. Smith, L. E. Govaert, J. Mater. Sci.: Mater. Med. (2010) 21, 89–97 9 V. Sedlarik, P. Kucharczyk, V. Kaasparkova, J. Drbohlav, A. Salakova, P. Saha, J. Appl. Polym. Sci, 116 (2010) 3, 1597–1602 10 V. Sedlarik, N. Saha, J. Sedlarikova, P. Saha, Macromolecular Symposia, 272 (2008), 100–103 11 M. Hrabalova, A. Gregorova, R. Wimmer, V. Sedlarik, M. Machovsky, N. Mundigler, J. Appl. Polym. Sci, 118 (2010) 3, 1534–1540 12 A. Gregorova, M. Hrabalova, R. Wimmer, J. Appl. Polym. Sci, 114 (2010) 5, 2616–2623 13 A. Gregorova, M. Hrabalova, R. Wimmer, Abstract of papers of the American chemical society, 235 (2008) 14 Tin-Sn in Lenntech periodic table, Available at: http://www.lenntech.com/periodic/elements/sn.htm, Cited 13. 2. 2010 15 J. L. Manzoori, M. Amjadi, D. Abolhasani, J. Hazard. Mater, B137 (2006), 1631–1635 16 A. Vesel, M. Mozetic, J. Kovac, A. Zalar, Appl. Surf. Sci., 253 (2006), 2941–2946 17 T. Vrlinic, A. Vesel, U. Cvelbar, M. Krajnc, M. Mozetic, Surf. Interface Anal., 39 (2007) 6, 476–481 18 A. Vesel, M. Mozetic, A. Drenik, N. Hauptman, M. Balat-Pichelin, Appl. Surf. Sci., 255 (2008) 5, 1759–1765 19 A. Vesel, K. Elersic, I. Junkar, B. Malic, Mater. Tehnol., 43 (2009) 6, 323–326 20 A. Asadinezhad, I. Novak, M. Lehocky, F. Bilek, A. Vesel, I. Junkar, P. Saha, A. Popelka, Molecules, 15 (2010) 2, 1007–1027 21 A. Asadinezhad, I. Novak, M. Lehocky, V. Sedlarik, A. Vesel, I. Junkar, P. Saha, I. Chodak, Plasma Processes Polym., 7 (2010) 6, 504–514 22 A. Vesel, M. Mozetic, A. Zalar, Surf. Interface Anal., 40 (2008) 3–4, 661–663 23 A. Vesel, M. Mozetic, A. Zalar, Vacuum, 82 (2008) 2, 248–251 24 A. Asadinezhad, I. Novak, M. Lehocky, V. Sedlarik, A. Vesel, P. Saha, I. Chodak. Colloids Surf. B Biointerfaces, 77 (2010) 2, 246–256 25 A. Vesel, A. Drenik, R. Zaplotnik, M. Balat-Pichelin, Surf. Interface Anal., 42 (2010) 1168–1171 26 A. Vesel, M. Mozetic, P. Panjan, N. Hauptman, M. Klanjsek-Gunde, M. Balat - Pichelin, Surf. Coat. Technol., 204 (2010) 9/10, 1503–1508 27 A. Vesel, M. Mozetic, A. Hladnik, J. Dolenc, J. Zule, S. Milosevic, N. Krstulovic, M. Klanjsek - Gunde, N. Hauptman, J. Phys. D: Appl. Phys., 40 (2007) 12, 3689–3696 28 A. Vesel, M. Mozetic, S. Strnad, K. Stana-Kleinschek, N. Hauptman, Z. Persin, Vacuum, 84 (2010) 1, 79–82 29 M. Mozetič, A. Zalar, P. Panjan, M. Bele, S. Pejovnik, R. Grmek, Thin Solid Films, 376 (2000), 5–8 30 A. Vesel, M. Mozetič, Vacuum, 61 (2001), 373–377 31 M. Klanjšek Gunde, M. Kunaver, M. Mozetič, P. Pelicon, J. Simčič, M. Budnar, M. Bele, Surf. coat. int., Part B, Coat. trans., 85 (2002), 115–121 32 M. Kunaver, M. Klanjšek Gunde, M. Mozetič, A. Hrovat, Dyes Pigm., 57 (2003), 235–243 33 M. Mozetič, Vacuum, 71 (2003), 237–240 34 M. Kunaver, M. Mozetič, M. Klanjšek Gunde, Thin Solid Films, 459 (2004), 115–117 35 U. Cvelbar, M. Mozetič, M. KlanjšekGunde, IEEE Trans. Plasma Sci., 33 (2005), 236–237 36 N. Krstulović, I. Labazan, S. Milošević, U. Cvelbar, A. Vesel, M. Mozetič, Appl. Phys., 39 (2006), 3799–3804 37 A. Drenik, A. Vesel, M. Mozetič, J. Nucl. Mater., 386–388 (2009), 893–895 38 M. Mozetič, Mater. Tehnol., 44 (2010) 4, 165-171 39 Drenik, U. Cvelbar, K. Ostrikov, M. Mozetic, J. Phys. D: Appl. Phys., 41 (2008) 11, 115201-1–115201-7 40 A. Ricard, M. Gaillard, V. Monna, A. Vesel, M. Mozetic, Surf. Coat. Tech., 142–144 (2001), 333–336 41 U. Cvelbar, K. Ostrikov, A. Drenik, M. Mozetic, Appl. Phys. Lett., 92 (2008) 13, 133505-1–133505-3 42 D. Babič, I. Poberaj, M. Mozetič, Rev. Sci. Instrum., 72 (2001), 4110–4114 43 I. Junkar, U. Cvelbar, A. Vesel, N. Hauptman, M. Mozetic, Plasma Processes Polym., 6 (2009) 10, 667–675 44 U. Cvelbar, M. Mozetic, I. Junkar, A. Vesel, J. Kovac, A. Drenik, T. Vrlinic, N. Hauptman, M. Klanjsek-Gunde, B. Markoli, N. Krstulovic, S. Milosevic, F. Gaboriau, T. Belmonte, Appl. Surf. Sci., 253 (2007) 21, 8669–8673 45 M. Gorjanc, V. Bukosek, M. Gorensek, M. Mozetic, Tex. Res. J., 80 (2010) 20, 2204–2213
utb.fulltext.sponsorship	This research was financially supported by the Ministry of Education, Youth and Sports of the Czech Republic (project No. 2B08071) and Operational Program Research and Development for Innovations co-funded by the European Regional Development Fund (ERDF, project No. CZ.1.05/2.1.00/03.0111). The authors acknowledge the financial support from the Ministry of Higher Education, Science and Technology of the Republic of Slovenia through the contract No. 3211-10-000057 (Center of Excellence for Polymer Materials and Technologies). Furthermore, this work was also co-supported Slovenian Research Agency (ARRS) and Science and Education Foundation of the Republic of Slovenia within the "Ad futura" programme and by the Ministry of Higher Education, Science and Technology of the Republic of Slovenia through the contract No. 3211-10-000057 (Center of Excellence Polymer Materials and Technologies).
utb.fulltext.projects	MSM 2B08071
utb.fulltext.projects	CZ.1.05/2.1.00/03.0111
utb.fulltext.projects	3211-10-000057