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1-methyl-3-phenyl-3-thiocyanato-1H,3H-quinoline-2,4-dione: A novel thiocyanating agent

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dc.title 1-methyl-3-phenyl-3-thiocyanato-1H,3H-quinoline-2,4-dione: A novel thiocyanating agent en
dc.contributor.author Klásek, Antonín
dc.contributor.author Mrkvička, Vladimír
dc.relation.ispartof Journal of Heterocyclic Chemistry
dc.identifier.issn 0022-152X Scopus Sources, Sherpa/RoMEO, JCR
dc.date.issued 2003
utb.relation.volume 40
utb.relation.issue 5
dc.citation.spage 747
dc.citation.epage 752
dc.type article
dc.language.iso en
dc.publisher Hetero Corporation en
dc.identifier.doi 10.1002/jhet.5570400501
dc.relation.uri http://onlinelibrary.wiley.com/doi/10.1002/jhet.5570400501/abstract
dc.subject thiokyanáty cs
dc.subject thiokyanace cs
dc.subject aminy cs
dc.subject thioly cs
dc.subject thiocyanates en
dc.subject thiocyanation en
dc.subject amines en
dc.subject thiols en
dc.description.abstract Under mild reaction conditions, the thiocyanato group is selectively transferred from 1-methyl-3-phenyl-3-thiocyanato-1H,3H-quinoline-2,4-dione (3) to some nucleophiles. Aliphatic primary and secondary amines are converted to S-cyanothiohydroxylamines, anilines afford p-thiocyanatoanilines, Wittig reagent is thiocyanated in ?-position, and thiols are oxidized to disulfides. en
utb.faculty Faculty of Technology
dc.identifier.uri http://hdl.handle.net/10563/1000242
utb.identifier.rivid RIV/70883521:28110/03:63501411
utb.identifier.obdid 11552939
utb.identifier.scopus 2-s2.0-0242361708
utb.identifier.wok 000186377000002
utb.source j-riv
utb.contributor.internalauthor Klásek, Antonín
utb.contributor.internalauthor Mrkvička, Vladimír
utb.fulltext.affiliation Antonín Klásek* and Vladimír Mrkvička Department of Chemistry and Environmental Technology, Faculty of Technology, Tomas Bata University, CZ-762 72 Zlín, Czech Republic
utb.fulltext.dates Received March 28, 2003
utb.fulltext.sponsorship This study was supported by the Ministry of Education, Youth and Sports of the Czech Republic (Grant No. MSM 265200015). The authors thank professor A. Lyčka (Research Institute of Organic Chemistry, Pardubice, Czech Republic) for measurement of the nmr spectra and Drs. B. Kralj and D. Žigon (Mass Spectrometry Center, Jožef Štefan Institute, Ljubljana, Slovenia) for mass spectral measurements. The authors are also indebted to Mrs. Hana Geržova (Faculty of Technology, Tomas Bata University in Zlin, Czech Republic) for technical help
utb.fulltext.projects MSM 265200015
utb.fulltext.faculty Faculty of Technology
utb.fulltext.ou Department of Chemistry and Environmental Technology
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