Reversible actuation ability upon light stimulation of the smart systems with controllably grafted graphene oxide with poly (glycidyl methacrylate) and PDMS elastomer: Effect of compatibility and graphene oxide reduction on the photo-actuation performance

Osička, Josef; Mrlík, Miroslav; Ilčíková, Markéta; Hanulíková, Barbora; Urbánek, Pavel; Sedlačík, Michal; Mosnáček, Jaroslav

dc.title	Reversible actuation ability upon light stimulation of the smart systems with controllably grafted graphene oxide with poly (glycidyl methacrylate) and PDMS elastomer: Effect of compatibility and graphene oxide reduction on the photo-actuation performance	en
dc.contributor.author	Osička, Josef
dc.contributor.author	Mrlík, Miroslav
dc.contributor.author	Ilčíková, Markéta
dc.contributor.author	Hanulíková, Barbora
dc.contributor.author	Urbánek, Pavel
dc.contributor.author	Sedlačík, Michal
dc.contributor.author	Mosnáček, Jaroslav
dc.relation.ispartof	Polymers
dc.identifier.issn	2073-4360 Scopus Sources, Sherpa/RoMEO, JCR
dc.date.issued	2018
utb.relation.volume	10
utb.relation.issue	8
dc.type	article
dc.language.iso	en
dc.publisher	MDPI AG
dc.identifier.doi	10.3390/polym10080832
dc.relation.uri	https://www.mdpi.com/2073-4360/10/8/832
dc.subject	dielectrics	en
dc.subject	dynamic mechanical analysis	en
dc.subject	graphene oxide	en
dc.subject	light-stimuli material	en
dc.subject	photo-responsive material	en
dc.subject	poly(glycidyl methacrylate)	en
dc.subject	reduction	en
dc.subject	SI-ATRP	en
dc.description.abstract	This study is focused on the controllable reduction of the graphene oxide (GO) during the surface-initiated atom transfer radical polymerization technique of glycidyl methacrylate (GMA). The successful modification was confirmed using TGA-FTIR analysis and TEM microscopy observation of the polymer shell. The simultaneous reduction of the GO particles was confirmed indirectly via TGA and directly via Raman spectroscopy and electrical conductivity investigations. Enhanced compatibility of the GO-PGMA particles with a polydimethylsiloxane (PDMS) elastomeric matrix was proven using contact angle measurements. Prepared composites were further investigated through the dielectric spectroscopy to provide information about the polymer chain mobility through the activation energy. Dynamic mechanical properties investigation showed an excellent mechanical response on the dynamic stimulation at a broad temperature range. Thermal conductivity evaluation also confirmed the further photo-actuation capability properties at light stimulation of various intensities and proved that composite material consisting of GO-PGMA particles provide systems with a significantly enhanced capability in comparison with neat GO as well as neat PDMS matrix. © 2018 by the authors.	en
utb.faculty	University Institute
dc.identifier.uri	http://hdl.handle.net/10563/1008150
utb.identifier.obdid	43879689
utb.identifier.scopus	2-s2.0-85051065250
utb.identifier.wok	000445410200025
utb.source	j-scopus
dc.date.accessioned	2018-08-29T08:26:56Z
dc.date.available	2018-08-29T08:26:56Z
dc.description.sponsorship	Czech Science Foundation [16-20361Y]; Ministry of Education, Youth and Sports of the Czech Republic-program NPU I [L01504]; Operational Program Research and Development for Innovations - the European Regional Development Fund (ERDF); project CPS-strengthening research capacity [CZ.1.05/2.1.00/19.0409]; [APVV-15-0545]; [APVV-14-0891]
dc.rights	Attribution 4.0 International
dc.rights.uri	https://creativecommons.org/licenses/by/4.0/
dc.rights.access	openAccess
utb.ou	Centre of Polymer Systems
utb.contributor.internalauthor	Osička, Josef
utb.contributor.internalauthor	Mrlík, Miroslav
utb.contributor.internalauthor	Hanulíková, Barbora
utb.contributor.internalauthor	Urbánek, Pavel
utb.contributor.internalauthor	Sedlačík, Michal
utb.fulltext.affiliation	Josef Osicka 1 https://orcid.org/0000-0002-4909-9350 , Miroslav Mrlik 1 https://orcid.org/0000-0001-6203-6795 , Marketa Ilcikova 2,, Barbora Hanulikova 1 , Pavel Urbanek 1 https://orcid.org/0000-0002-9090-4681 , Michal Sedlacik 1, https://orcid.org/0000-0003-3918-5084 and Jaroslav Mosnacek 2,3 https://orcid.org/0000-0001-9160-590X 1 Centre of Polymer Systems, University Institute, Tomas Bata University in Zlín, Trida T. Bati 5678, 760 01 Zlín, Czech Republic; osicka@utb.cz (J.O.); mrlik@utb.cz (M.M.); hanulikova@utb.cz (B.H.); urbanek@utb.cz (P.U.) 2 Polymer Institute, Slovak Academy of Sciences, Dúbravska cesta 9, 845 41 Bratislava, Slovakia; upolmosj@savba.sk 3 Centre for Advanced Materials Application, Slovak Academy of Sciences, Dúbravska cesta 9, 845 11 Bratislava, Slovakia * Correspondence: upolmail@savba.sk (M.I.); msedlacik@utb.cz (M.S.); Tel.: +421-232-294-347 (M.I.); +420-576-038-027 (M.S.)
utb.fulltext.dates	Received: 20 June 2018 Accepted: 26 July 2018 Published: 28 July 2018
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utb.fulltext.sponsorship	This research was funded by the Czech Science Foundation (no. 16-20361Y) for financial support. This work was also supported by the Ministry of Education, Youth and Sports of the Czech Republic-program NPU I (LO1504). Authors M.I. and J.M. gratefully acknowledge APVV-15-0545 and APVV-14-0891 for financial support. The TGA-FTIR results obtained in this article were possibly collected using the device brought from the financial support of Operational Program Research and Development for Innovations co-funded by the European Regional Development Fund (ERDF) and national budget of the Czech Republic within the framework of project CPS-strengthening research capacity (no. CZ.1.05/2.1.00/19.0409).
utb.scopus.affiliation	Centre of Polymer Systems, University Institute, Tomas Bata University in Zlín, Trida T. Bati 5678, Zlín, Czech Republic; Polymer Institute, Slovak Academy of Sciences, Dúbravska cesta 9, Bratislava, Slovakia; Centre for Advanced Materials Application, Slovak Academy of Sciences, Dúbravska cesta 9, Bratislava, Slovakia
utb.fulltext.projects	16-20361Y
utb.fulltext.projects	NPU I (LO1504)
utb.fulltext.projects	APVV-15-0545
utb.fulltext.projects	APVV-14-0891
utb.fulltext.projects	CZ.1.05/2.1.00/19.0409