Structure and morphology of linear polyethylene extrudates induced by elongational flow

Rybnikář, František; Kaszonyiová, Martina; Čermák, Roman; Habrová, Veronika; Obadal, Martin

dc.title	Structure and morphology of linear polyethylene extrudates induced by elongational flow	en
dc.contributor.author	Rybnikář, František
dc.contributor.author	Kaszonyiová, Martina
dc.contributor.author	Čermák, Roman
dc.contributor.author	Habrová, Veronika
dc.contributor.author	Obadal, Martin
dc.relation.ispartof	Journal of Applied Polymer Science
dc.identifier.issn	0021-8995 Scopus Sources, Sherpa/RoMEO, JCR
dc.date.issued	2013
utb.relation.volume	128
utb.relation.issue	3
dc.citation.spage	1665
dc.citation.epage	1672
dc.type	article
dc.language.iso	en
dc.publisher	John Wiley & Sons, Inc.	en
dc.identifier.doi	10.1002/app.38323
dc.relation.uri	http://onlinelibrary.wiley.com/doi/10.1002/app.38323/abstract
dc.subject	crystallization	en
dc.subject	extrusion	en
dc.subject	morphology	en
dc.subject	polyolefins	en
dc.description.abstract	This study focuses on the structure, morphology, and properties of linear polyethylene (PE) profiles manufactured by continuous extrusion. High level of chain orientation was achieved using specific flow and processing conditions. An extrusion die with semihyperbolic convergency was used to generate high percentage of elongational flow and chain extension. Simultaneously, high extrusion pressure and relatively low melt temperature led to flow-induced crystallization of PE extended chains. The structure of PE tapes consists of crystal aggregates with different level of orientation and crystallinity. © 2012 Wiley Periodicals, Inc.	en
utb.faculty	Faculty of Technology
dc.identifier.uri	http://hdl.handle.net/10563/1003149
utb.identifier.obdid	43869989
utb.identifier.scopus	2-s2.0-84873709262
utb.identifier.wok	000314927200040
utb.identifier.coden	JAPNA
utb.source	j-scopus
dc.date.accessioned	2013-02-24T06:54:10Z
dc.date.available	2013-02-24T06:54:10Z
dc.description.sponsorship	Czech Ministry of Education, Youth, and Sports in the RD project [MSM 7088352102]; CEBIA Tech [CZ.1.05/2.1.00/03.0089]
utb.contributor.internalauthor	Rybnikář, František
utb.contributor.internalauthor	Kaszonyiová, Martina
utb.contributor.internalauthor	Čermák, Roman
utb.fulltext.affiliation	Frantisek Rybnikar, 1 Martina Kaszonyiova, 1 Roman Cermak, 2 Veronika Habrova, 3 Martin Obadal 4 1 Department of Production Engineering, Tomas Bata University in Zlin, Zlin, Czech Republic 2 Department of Polymer Engineering, Tomas Bata University in Zlin, Zlin, Czech Republic 3 Polymer Institute, Brno, Czech Republic 4 Borealis Polyolefine GmbH, Linz, Austria Correspondence to: M. Kaszonyiova (E-mail: mhribova@ft.utb.cz)
utb.fulltext.dates	Received 27 March 2012 accepted 4 July 2012 published online 26 July 2012
utb.fulltext.references	1. Peterlin, A.; Ingram, P.; Kiho, H. Makromol. Chem. 1965, 86, 294. 2. Korsukov, V. E.; Marikhin, V. A.; Myasnikova, L. P.; Novak, I. I.; J. Polym. Sci. Part C: Polym. Symp. 1973, 42, 847. 3. Myasnikova, L. P. Plast. Kautsch. 1986, 33, 121. 4. Elyashevich, G. K.; Karpov, E. A.; Kudasheva, O. V.; Rosova, E. Mech. Time-Depend. Mater. 1999, 3, 319. 5. Song, J.; Prox, M.; Weber, A.; Ehrenstein, G. W. In: Polypropylene: Structure, Blends; Composites; Karger-Kocsis, J., Ed.; Chapman & Hall: London, 1995; p 273–294. 6. McHugh, A. J. J. Appl. Polym. Sci. 1975, 19, 125. 7. Southern, J. H.; Porter, R. S. J. Appl. Polym. Sci. 1970, 14, 2305. 8. Southern, J. H.; Porter R. S.; Bair H. E. J. Polym. Sci., 1972, 1135. 9. Hare, J. B.; Cucolo, J. A. Midland Macromolecular Monographs (Flow-Induced Cryst. Polym. Syst.) 1979, 6, 175. 10. Pornimit, B.; Ehrenstein, G. W. Kunststoffe 1989, 79, 43. 11. Pornimit, B.; Ehrenstein, G. W. Adv. Polym. Technol. 1992, 11, 91. 12. McHugh, A. J.; Tree, D. A.; Pornnimit, B.; Ehrenstein, G. W. Int. Polym. Proc. 1991, 6, 208. 13. Huang, H. X. Polym. Eng. Sci. 1998, 38, 1805. 14. Huang, H. X. J. Mater. Sci. Lett. 1999, 18, 225. 15. Ehrenstein, G. W.; Maertin, C. Kunststoffe 1985, 75, 20. 16. Pendse, A. V.; Collier, J. R. J. Appl. Polym. Sci. 1996, 59, 1305. 17. Obadal, M.; Čermák, R.; Stoklasa, K.; Habrová, V. Plast. Rubber Compos. 2004, 33, 295. 18. Čermák, R.; Obadal, M.; Habrová, V.; Stoklasa K.; Verney, V.; Commereuc, S.; Fraïssé, F. Rheol. Acta 2006, 45, 366–373. 19. Scherrer, P. In: X-Ray Diffraction Methods in Polymer Science; Alexander, L. E., Eds.; Wiley-Interscience: New York, 1969; 582 p. 20. Wunderlich, B. Thermal Analysis; Academic Press: New York, 1990.
utb.fulltext.sponsorship	This research was financially supported by the Czech Ministry of Education, Youth, and Sports in the R&D project under the title ‘Modelling and Control of Processing Procedures of Natural and Synthetic Polymers’, No. MSM 7088352102 and ‘CEBIA Tech’, No. CZ.1.05/2.1.00/03.0089.