1-methyl-3-phenyl-3-thiocyanato-1H,3H-quinoline-2,4-dione: A novel thiocyanating agent

Klásek, Antonín; Mrkvička, Vladimír

dc.title	1-methyl-3-phenyl-3-thiocyanato-1H,3H-quinoline-2,4-dione: A novel thiocyanating agent	en
dc.contributor.author	Klásek, Antonín
dc.contributor.author	Mrkvička, Vladimír
dc.relation.ispartof	Journal of Heterocyclic Chemistry
dc.identifier.issn	0022-152X Scopus Sources, Sherpa/RoMEO, JCR
dc.date.issued	2003
utb.relation.volume	40
utb.relation.issue	5
dc.citation.spage	747
dc.citation.epage	752
dc.type	article
dc.language.iso	en
dc.publisher	Hetero Corporation	en
dc.identifier.doi	10.1002/jhet.5570400501
dc.relation.uri	http://onlinelibrary.wiley.com/doi/10.1002/jhet.5570400501/abstract
dc.subject	thiokyanáty	cs
dc.subject	thiokyanace	cs
dc.subject	aminy	cs
dc.subject	thioly	cs
dc.subject	thiocyanates	en
dc.subject	thiocyanation	en
dc.subject	amines	en
dc.subject	thiols	en
dc.description.abstract	Under mild reaction conditions, the thiocyanato group is selectively transferred from 1-methyl-3-phenyl-3-thiocyanato-1H,3H-quinoline-2,4-dione (3) to some nucleophiles. Aliphatic primary and secondary amines are converted to S-cyanothiohydroxylamines, anilines afford p-thiocyanatoanilines, Wittig reagent is thiocyanated in ?-position, and thiols are oxidized to disulfides.	en
utb.faculty	Faculty of Technology
dc.identifier.uri	http://hdl.handle.net/10563/1000242
utb.identifier.rivid	RIV/70883521:28110/03:63501411
utb.identifier.obdid	11552939
utb.identifier.scopus	2-s2.0-0242361708
utb.identifier.wok	000186377000002
utb.source	j-riv
utb.contributor.internalauthor	Klásek, Antonín
utb.contributor.internalauthor	Mrkvička, Vladimír
utb.fulltext.affiliation	Antonín Klásek* and Vladimír Mrkvička Department of Chemistry and Environmental Technology, Faculty of Technology, Tomas Bata University, CZ-762 72 Zlín, Czech Republic
utb.fulltext.dates	Received March 28, 2003
utb.fulltext.sponsorship	This study was supported by the Ministry of Education, Youth and Sports of the Czech Republic (Grant No. MSM 265200015). The authors thank professor A. Lyčka (Research Institute of Organic Chemistry, Pardubice, Czech Republic) for measurement of the nmr spectra and Drs. B. Kralj and D. Žigon (Mass Spectrometry Center, Jožef Štefan Institute, Ljubljana, Slovenia) for mass spectral measurements. The authors are also indebted to Mrs. Hana Geržova (Faculty of Technology, Tomas Bata University in Zlin, Czech Republic) for technical help
utb.fulltext.projects	MSM 265200015
utb.fulltext.faculty	Faculty of Technology
utb.fulltext.ou	Department of Chemistry and Environmental Technology