A method for mitigating degradation effects on polyamide textile yarn during mechanical recycling

Abstract

The phenomenon of fast fashion has resulted in high yarn consumption and growing textile waste from both manufacturing and consumers. Rising environmental awareness and evolving legislation, including landfill restrictions, have prompted the search for sustainable recycling methods to manage textile end-of-life. This study investigates the mechanical recycling of polyamide 6.6 (PA66) yarn using a chain extender (Joncryl) and antioxidant (Irganox). Thermogravimetric analysis (TGA) confirmed that thermal stability in recycled PA66 was maintained compared to the original yarn, and the presence of Joncryl further enhanced this stability. Oxidative-onset temperature (OOT), measured by differential scanning calorimetry (DSC), supported these improvements. Gas chromatography-mass spectrometry (GC/MS) identified key degradation products, which were correlated with changes in the polymer matrix. Mechanical testing showed a 31% decrease in Young's modulus after initial recycling, which was reversed with further processing. This behavior suggests the formation of shortened semi-crystalline chains and new linkages promoted by Joncryl. Viscosity and limiting viscosity number increased by up to 50%, depending on both additive concentrations. Overall, Joncryl and Irganox enhanced viscosity, mechanical strength, and notably thermal stability, confirming their suitability for recyclable textile-grade PA66 yarns.