Electrospun polyurethane nanofibers coated with polyaniline/polyvinyl alcohol as ultrafiltration membranes for the removal of ethinylestradiol hormone micropollutant from aqueous phase

Yasir, Muhammad; Asabuwa Ngwabebhoh, Fahanwi; Šopík, Tomáš; Ali, Hassan; Sedlařík, Vladimír

dc.title	Electrospun polyurethane nanofibers coated with polyaniline/polyvinyl alcohol as ultrafiltration membranes for the removal of ethinylestradiol hormone micropollutant from aqueous phase	en
dc.contributor.author	Yasir, Muhammad
dc.contributor.author	Asabuwa Ngwabebhoh, Fahanwi
dc.contributor.author	Šopík, Tomáš
dc.contributor.author	Ali, Hassan
dc.contributor.author	Sedlařík, Vladimír
dc.relation.ispartof	Journal of Environmental Chemical Engineering
dc.identifier.issn	2213-2929 Scopus Sources, Sherpa/RoMEO, JCR
dc.identifier.issn	2213-3437 Scopus Sources, Sherpa/RoMEO, JCR
dc.date.issued	2022
utb.relation.volume	10
utb.relation.issue	3
dc.type	article
dc.language.iso	en
dc.publisher	Elsevier Ltd
dc.identifier.doi	10.1016/j.jece.2022.107811
dc.relation.uri	https://www.sciencedirect.com/science/article/pii/S2213343722006844
dc.subject	hormone removal	en
dc.subject	electrospun nanofibers	en
dc.subject	in situ coating	en
dc.subject	adsorption	en
dc.subject	water remediation	en
dc.description.abstract	Estrogenic hormones at significant levels are a serious cause of fish femininity, breast and ovarian cancer as a consequence of hormonal imbalance. This study reports the fabrication of electrospun polyurethane (PU) nanofibers modified by coating with polyaniline/polyvinyl alcohol (PANI/PVA) to form filtration membranes for the enhanced removal of ethinylestradiol (EE2) estrogenic hormone. Structural and morphological character-ization was performed by FTIR, SEM and optical microscopy, while the detection and quantification of EE2 were analysed using HPLC. To understand the material characteristics, the feasibility of the results based on contact time and kinetics to determine the adsorption capacity coated PU nanofibers was further investigated. Findings demonstrated that EE2 best fitted pseudo-second-order kinetics. Furthermore, the adsorption process was opti-mised via response surface methodology using a central composite design model by varying parameters such as pH, temperature, the concentration of adsorbate, and adsorbent dosage to determine. It was found that the modified PU membranes had a maximum adsorption capacity of 2.11 mg/g and high removal percentage effi-ciency of ~82.20% for EE2. Adsorption mechanism and thermodynamics were also evaluated, and the results depicted the adsorption process of EE2 occurred via intraparticle diffusion and was exothermic in nature. Finally, a reusability study was done over six adsorption-desorption cycles to test the consistent effectiveness of the modified PU membrane, which remained above 80% removal capacity. Overall, the findings indicate that treated PU with stabilized PANI particles possess the potential to form an effective adsorbent for eradicating EE2 and other estrogenic hormones from the environment.	en
utb.faculty	University Institute
dc.identifier.uri	http://hdl.handle.net/10563/1010989
utb.identifier.obdid	43883911
utb.identifier.scopus	2-s2.0-85130217331
utb.identifier.wok	000796244400001
utb.source	j-scopus
dc.date.accessioned	2022-06-10T07:48:32Z
dc.date.available	2022-06-10T07:48:32Z
dc.description.sponsorship	IGA/CPS/2022/003; Ministerstvo Školství, Mládeže a Tělovýchovy, MŠMT: RP/CPS/2022/002, RP/CPS/2022/005
dc.description.sponsorship	Ministry of Education, Youth and Sports of Czech Republic [IGA/CPS/2022/003, DKRVO RP/CPS/2022/002]; Internal Grant Agency of TBU in Zlin [RP/CPS/2022/005]
utb.ou	Centre of Polymer Systems
utb.contributor.internalauthor	Yasir, Muhammad
utb.contributor.internalauthor	Asabuwa Ngwabebhoh, Fahanwi
utb.contributor.internalauthor	Šopík, Tomáš
utb.contributor.internalauthor	Ali, Hassan
utb.contributor.internalauthor	Sedlařík, Vladimír
utb.fulltext.affiliation	Muhammad Yasir , Fahanwi Asabuwa Ngwabebhoh , Tomáš Šopík , Hassan Ali , Vladimír Sedlařík Centre of Polymer Systems, University Institute, Tomas Bata University in Zlín, Třída Tomáše Bati 5678, 76001 Zlín, Czech Republic * Corresponding authors. E-mail addresses: yasir@utb.cz (M. Yasir), sedlarik@utb.cz (V. Sedlařík).
utb.fulltext.dates	Received 31 January 2022 Received in revised form 19 April 2022 Accepted 25 April 2022 Available online 28 April 2022
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utb.fulltext.sponsorship	The authors gratefully acknowledge the financial support from the Ministry of Education, Youth and Sports of Czech Republic (DKRVO RP/CPS/2022/002 and RP/CPS/2022/005), the Internal Grant Agency of TBU in Zlin (grant no. IGA/CPS/2022/003). We would also like to acknowledge the Centre of Polymer Systems (CPS) situated at Tomas Bata University in Zlin, Czech Republic, to use the available research facilities to conduct this research work.
utb.wos.affiliation	[Yasir, Muhammad; Ngwabebhoh, Fahanwi Asabuwa; Sopik, Tomas; Ali, Hassan; Sedlarik, Vladimir] Tomas Bata Univ Zlin, Univ Inst, Ctr Polymer Syst, Trida Tomas Bati 5678, Zlin 76001, Czech Republic
utb.scopus.affiliation	Centre Of Polymer Systems, University Institute, Tomas Bata University In Zlín, Trída Tomáše Bati 5678, Zlín, 76001, Czech Republic
utb.fulltext.projects	RP/CPS/2022/002
utb.fulltext.projects	RP/CPS/2022/005
utb.fulltext.faculty	University Institute
utb.fulltext.ou	Centre of Polymer Systems