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Controllably coated graphene oxide particles with enhanced compatibility with poly(ethylene-co-propylene) thermoplastic elastomer for excellent photo-mechanical actuation capability

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dc.title Controllably coated graphene oxide particles with enhanced compatibility with poly(ethylene-co-propylene) thermoplastic elastomer for excellent photo-mechanical actuation capability en
dc.contributor.author Osička, Josef
dc.contributor.author Mrlík, Miroslav
dc.contributor.author Ilčíková, Markéta
dc.contributor.author Krupa, Igor
dc.contributor.author Sobolčiak, Patrik
dc.contributor.author Plachý, Tomáš
dc.contributor.author Mosnáček, Jaroslav
dc.relation.ispartof Reactive and Functional Polymers
dc.identifier.issn 1381-5148 Scopus Sources, Sherpa/RoMEO, JCR
dc.date.issued 2020
utb.relation.volume 148
dc.type article
dc.language.iso en
dc.publisher Elsevier B.V.
dc.identifier.doi 10.1016/j.reactfunctpolym.2020.104487
dc.relation.uri https://www.sciencedirect.com/science/article/pii/S1381514819310004
dc.subject Graphene oxide en
dc.subject ATRP en
dc.subject Compatibility en
dc.subject Vistamaxx en
dc.subject Grafting en
dc.subject Stimuli responsive properties en
dc.description.abstract This paper reports the utilization of the controllable coating via SI-ATRP technique as a promising approach for controlling stimuli-responsive capabilities of graphene oxide (GO) based nanocomposites. Various polymer brushes with controlled molar mass and narrow dispersity were grown from the surface of GO particles. Modification of GO with poly(methyl methacrylate) and poly(n-butyl methacrylate) was proved by transmission electron microscopy, thermogravimetric analysis with online FTIR recording and finally by X-ray photoelectron spectroscopy (XPS). Densities of GO-based materials were investigated and conductivity measurements showed the increase values. XPS and Raman shift was used to confirm the GO particles reduction. A compatibility of the filler with propylene-based elastomer was elucidated by melt rheology. The light-induced actuation capability was investigated on composite samples to show, that polymer hybrid particles based on GO have better compatibility with the polymer matrix and thus their proper dispersibility was significantly improved. In addition the plasticizing effect of the short polymer grafts present on the GO filler surface has the crucial impact on the matrix stiffness and thus the ability of composite material to reversibly respond to the external light stimulation. © 2020 Elsevier B.V. en
utb.faculty University Institute
dc.identifier.uri http://hdl.handle.net/10563/1009578
utb.identifier.obdid 43881698
utb.identifier.scopus 2-s2.0-85078527262
utb.identifier.wok 000518708000007
utb.identifier.coden RFPOF
utb.source j-scopus
dc.date.accessioned 2020-03-02T12:28:38Z
dc.date.available 2020-03-02T12:28:38Z
dc.description.sponsorship Qatar University Collaborative High Impact Grant [QUHI-CENG-18/19-1]; Grant Agency of the Czech RepublicGrant Agency of the Czech Republic [16-20361Y]; Ministry of Education, Youth and Sports of the Czech Republic program NPU I [LO1504]; Research & Innovation Operational Programme - ERDF [313021T081]; VEGAVedecka grantova agentura MSVVaS SR a SAV (VEGA) [2/0129/19]; European Regional Development Fund (ERDF)European Union (EU); national budget of Czech Republic [CZ.1.05/2.1.00/19.0409]; National Science Centre, Poland [UMO-2016/23/P/ST5/02131]; European Unions's Horizon 2020 research and innovation programme under Marie Sklodowska-Curie grantEuropean Union (EU) [665778]; Operational Program Research and Development for innovations
utb.ou Centre of Polymer Systems
utb.contributor.internalauthor Osička, Josef
utb.contributor.internalauthor Mrlík, Miroslav
utb.contributor.internalauthor Plachý, Tomáš
utb.fulltext.affiliation Josef Osicka a, Miroslav Mrlik a⁎, Marketa Ilcikova b,c, Igor Krupa d⁎⁎, Patrik Sobolčiak d, Tomáš Plachý a, Jaroslav Mosnáček b,e⁎⁎⁎ a Centre of Polymer Systems, University Institute, Tomas Bata University in Zlin, Trida T. Bati 5678, 760 01 Zlin, Czech Republic b Polymer Institute, Slovak Academy of Sciences, Dubravska cesta 9, 845 41 Bratislava 45, Slovakia c Department of Chemistry, Lodz University of Technology, Institute of Polymer and Dye Technology, 90 924 Lodz, Poland d Center for Advanced Materials, Qatar University, P. O. Box 2713, Doha, Qatar e Centre for Advanced Materials Application, Slovak Academy of Sciences, Dúbravska cesta 9, 845 11 Bratislava, Slovakia ⁎ Correspondence to: M. Mrlík, Centre of Polymer Systems, University Institute, Tomas Bata University in Zlin, Trida T. Bati 5678, 760 01 Zlin, Czech Republic ⁎⁎ Corresponding author. ⁎⁎⁎ Correspondence to: J. Mosnáček, Polymer Institute, Slovak Academy of Sciences, Dubravska cesta 9, 845 41 Bratislava 45, Slovakia. E-mail addresses: mrlik@utb.cz (M. Mrlik), igor.krupa@qu.edu.qa (I. Krupa), jaroslav.mosnacek@savba.sk (J. Mosnáček).
utb.fulltext.dates Received 20 September 2019 Received in revised form 9 January 2020 Accepted 10 January 2020 Available online 11 January 2020
utb.fulltext.sponsorship This research was funded by Qatar University Collaborative High Impact Grant QUHI-CENG-18/19-1 . The findings achieved herein are solely the responsibility of the authors. Authors also gratefully thanks to the Grant Agency of the Czech Republic (no. 16-20361Y ) for financial support. This work was also supported by the Ministry of Education, Youth and Sports of the Czech Republic – program NPU I ( LO1504 ). This study was also performed during the implementation of the project Building-up Centre for advanced materials application of the Slovak Academy of Sciences, ITMS project code 313021T081 supported by Research & Innovation Operational Programme funded by the ERDF. JM also acknowledge for financial support to project VEGA 2/0129/19 . This article (specify by the fact) was also written with support of Operational Program Research and Development for innovations co-funded by the European Regional Development Fund (ERDF) and national budget of Czech Republic, within the framework of project CPS - strengthening research capacity (reg. number: CZ.1.05/2.1.00/19.0409). M. I. also thank to National Science Centre , Poland for the financial support through POLONEZ project number UMO-2016/23/P/ST5/02131 . This project is carried out under POLONEZ program which has received funding from the European Unions's Horizon 2020 research and innovation programme under Marie Sklodowska-Curie grant agreement. No 665778
utb.wos.affiliation [Osicka, Josef; Mrlik, Miroslav; Plachy, Tomas] Tomas Bata Univ Zlin, Univ Inst, Ctr Polymer Syst, Trida T Bali 5678, Zlin 76001, Czech Republic; [Ilcikova, Marketa; Mosnacek, Jaroslav] Slovak Acad Sci, Polymer Inst, Dubravska Cesta 9, Bratislava 84541 45, Slovakia; [Ilcikova, Marketa] Lodz Univ Technol, Inst Polymer & Dye Technol, Dept Chem, PL-90924 Lodz, Poland; [Krupa, Igor; Sobolciak, Patrik] Qatar Univ, Ctr Adv Mat, POB 2713, Doha, Qatar; [Mosnacek, Jaroslav] Slovak Acad Sci, Ctr Adv Mat Applicat, Dubravska Cesta 9, Bratislava 84511, Slovakia
utb.scopus.affiliation Centre of Polymer Systems, University Institute, Tomas Bata University in Zlin, Trida T. Bati 5678, Zlin, 760 01, Czech Republic; Polymer Institute, Slovak Academy of Sciences, Dubravska cesta 9, Bratislava 45, 845 41, Slovakia; Department of Chemistry, Lodz University of Technology, Institute of Polymer and Dye Technology, Lodz, 90 924, Poland; Center for Advanced Materials, Qatar University, P. O. Box 2713, Doha, Qatar; Centre for Advanced Materials Application, Slovak Academy of Sciences, Dúbravska cesta 9, Bratislava, 845 11, Slovakia
utb.fulltext.projects QUHI-CENG-18/19-1
utb.fulltext.projects 16-20361Y
utb.fulltext.projects LO1504
utb.fulltext.projects 313021T081
utb.fulltext.projects VEGA 2/0129/19
utb.fulltext.projects CZ.1.05/2.1.00/19.0409
utb.fulltext.projects UMO-2016/23/P/ST5/02131
utb.fulltext.projects 665778
utb.fulltext.faculty University Institute
utb.fulltext.faculty University Institute
utb.fulltext.faculty University Institute
utb.fulltext.ou Centre of Polymer Systems
utb.fulltext.ou Centre of Polymer Systems
utb.fulltext.ou Centre of Polymer Systems
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