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Plasma polymerization of 2-isopropenyl-2-oxazoline: Improvement of the coating stability by co-polymerization with 1-octene

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dc.title Plasma polymerization of 2-isopropenyl-2-oxazoline: Improvement of the coating stability by co-polymerization with 1-octene en
dc.contributor.author Zanini, Stefano
dc.contributor.author Lehocký, Marián
dc.contributor.author López García, Jorge Andrés
dc.contributor.author Riccardi, Claudia
dc.relation.ispartof Thin Solid Films
dc.identifier.issn 0040-6090 Scopus Sources, Sherpa/RoMEO, JCR
dc.date.issued 2019
utb.relation.volume 677
dc.citation.spage 55
dc.citation.epage 61
dc.type article
dc.language.iso en
dc.publisher Elsevier
dc.identifier.doi 10.1016/j.tsf.2019.03.014
dc.relation.uri https://www.sciencedirect.com/science/article/pii/S0040609019301579
dc.subject Plasma Polymerization en
dc.subject 2-isopropenyl-2-oxazoline en
dc.subject 1-octene en
dc.subject Attenuated Total reflectance Fourier transform infrared spectroscopy en
dc.subject zeta-Potential en
dc.description.abstract Thin films were deposited by plasma co-polymerization of 2-isopropenyl-2-oxazoline and 1-octene, varying the total monomers flow rate and the 1-octene percentage in the mixture. The coatings wettability was evaluated by water contact angle measurements, while their stability was investigated by immersion in Phosphate Buffer Saline at 37 °C. The chemical characterization of the coatings, performed by means of Attenuated Total Reflectance Fourier Transform Infrared spectroscopy and by reaction with poly(acrylic acid), assessed a partial retention of the reactive oxazoline ring, as already observed for plasma polymerization of several oxazoline monomers alone. However, the addition of 1-octene had significant effects on the coating stability and on the surface availability of reactive oxazoline rings. Compared to those obtained by plasma polymerization of 2-isopropenyl-2-oxazoline alone, this coatings exhibited higher stability in aqueous environments but lower reactivity towards carboxylic acid groups. © 2019 Elsevier B.V. en
utb.faculty University Institute
dc.identifier.uri http://hdl.handle.net/10563/1008587
utb.identifier.obdid 43880439
utb.identifier.scopus 2-s2.0-85063140437
utb.identifier.wok 000464982900008
utb.identifier.coden THSFA
utb.source j-scopus
dc.date.accessioned 2019-07-08T11:59:57Z
dc.date.available 2019-07-08T11:59:57Z
dc.description.sponsorship Czech Science Foundation [17-10813S]
utb.ou Centre of Polymer Systems
utb.contributor.internalauthor Lehocký, Marián
utb.contributor.internalauthor López García, Jorge Andrés
utb.fulltext.affiliation Stefano Zanini a*, Marian Lehocky b, Jorge Lopez-Garcia b, Claudia Riccardi a* a Università degli Studi di Milano-Bicocca, Dipartimento di Fisica “G. Occhialini”, Piazza della Scienza, 3 I-20126 Milano, Italy b Centre of Polymer Systems, Tomas Bata University in Zlín, Trida T. Bati 5678, 760 01 Zlín, Czech Republic * Corresponding authors at: Università degli Studi di Milano-Bicocca, Dipartimento di Fisica “G. Occhiaelini”, Piazza della Scienza, 3 I-20126 Milano, Italy E-mail addresses: stefano.zanini@mib.infn.it (S. Zanini), claudia.riccardi@mib.infn.it (C. Riccardi).
utb.fulltext.dates Received 6 August 2018 Received in revised form 18 February 2019 Accepted 15 March 2019 Available online 16 March 2019
utb.wos.affiliation [Zanini, Stefano; Riccardi, Claudia] Univ Milano Bicocca, Dipartimento Fis G Occhialini, Piazza Sci 3, I-20126 Milan, Italy; [Lehocky, Marian; Lopez-Garcia, Jorge] Tomas Bata Univ Zlin, Ctr Polymer Syst, Trida T Bali 5678, Zlin 76001, Czech Republic
utb.scopus.affiliation Università degli Studi di Milano-Bicocca, Dipartimento di Fisica “G. Occhialini”, Piazza della Scienza, Milano, 3 I-20126, Italy; Centre of Polymer Systems, Tomas Bata University in Zlín, Trida T. Bati 5678, Zlín, 760 01, Czech Republic
utb.fulltext.faculty University Institute
utb.fulltext.faculty University Institute
utb.fulltext.ou Centre of Polymer Systems
utb.fulltext.ou Centre of Polymer Systems
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