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Effect of a hybrid zinc stearate-silver system on the properties of polylactide and its abiotic and the biotic degradation and antimicrobial activity thereof

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dc.title Effect of a hybrid zinc stearate-silver system on the properties of polylactide and its abiotic and the biotic degradation and antimicrobial activity thereof en
dc.contributor.author Jandíková, Gabriela
dc.contributor.author Štoplová, Petra
dc.contributor.author Di Martino, Antonio
dc.contributor.author Stloukal, Petr
dc.contributor.author Kucharczyk, Pavel
dc.contributor.author Machovský, Michal
dc.contributor.author Sedlařík, Vladimír
dc.relation.ispartof Chinese Journal of Polymer Science (English Edition)
dc.identifier.issn 0256-7679 Scopus Sources, Sherpa/RoMEO, JCR
dc.date.issued 2018
utb.relation.volume 36
utb.relation.issue 8
dc.citation.spage 925
dc.citation.epage 933
dc.type article
dc.language.iso en
dc.publisher Springer Verlag
dc.identifier.doi 10.1007/s10118-018-2120-0
dc.relation.uri https://link.springer.com/article/10.1007/s10118-018-2120-0
dc.subject Polylactide en
dc.subject Composite en
dc.subject Biodegradation en
dc.subject Zinc stearate en
dc.subject Silver en
dc.subject Antimicrobial en
dc.description.abstract This work investigates the degradation and properties of a thermoplastically prepared composite comprising a polylactide/hybrid zinc stearate-silver system. The influence of the zinc stearate-silver system on the properties of the composite is investigated by electron microscopy, differential scanning calorimetry and tensile tests. Furthermore, the antimicrobial activities of the systems are examined. The degradation behaviour of the composites is studied in both abiotic and biotic (composting) environments at an elevated temperature of 58 °C. The results reveal good dispersion of the additive in the PLA matrix, a stabilizing effect exerted by the same on the polylactide matrix during processing, and slight reduction in glass transition temperature. The zinc stearate-silver component also reduces brittleness and extends elongation of the composite. Abiotic hydrolysis is not significantly affected, which is in contrast with pure PLA, although mineralization during the early stage of biodegradation increases noticeably. The composite exhibits antimicrobial activity, even at the lowest dosage of the zinc stearate/silver component (1 wt%). Moreover, Ag and Zn contents were found to be present in the composite during abiotic hydrolysis, which was demonstrated by minimal diffusion of Ag ions from the matrix and very extensive washing of compounds that contained Zn. © 2018, Chinese Chemical Society, Institute of Chemistry, Chinese Academy of Sciences and Springer-Verlag GmbH Germany, part of Springer Nature. en
utb.faculty University Institute
dc.identifier.uri http://hdl.handle.net/10563/1008082
utb.identifier.obdid 43878228
utb.identifier.scopus 2-s2.0-85045937390
utb.identifier.wok 000436565500004
utb.identifier.coden CJPSE
utb.source j-scopus
dc.date.accessioned 2018-07-27T08:47:43Z
dc.date.available 2018-07-27T08:47:43Z
dc.description.sponsorship Czech Science Foundation [17-16928Y]; Ministry of Education, Youth and Sports of the Czech Republic within the NPU I programme [LO1504]
utb.ou Centre of Polymer Systems
utb.contributor.internalauthor Jandíková, Gabriela
utb.contributor.internalauthor Štoplová, Petra
utb.contributor.internalauthor Di Martino, Antonio
utb.contributor.internalauthor Stloukal, Petr
utb.contributor.internalauthor Kucharczyk, Pavel
utb.contributor.internalauthor Machovský, Michal
utb.contributor.internalauthor Sedlařík, Vladimír
utb.fulltext.affiliation Gabriela Jandíková, Petra Stoplova, Antonio Di Martino, Petr Stloukal, Pavel Kucharczyk* , Michal Machovsky, and Vladimir Sedlarik Centre of Polymer Systems, University Institute, Tomas Bata University in Zlin, tr. Tomas Bati 5678, 760 01 Zlin, Czech Republic * Corresponding author: E-mail p.kucharczyk@seznam.cz
utb.fulltext.dates Received December 2, 2017; Accepted February 3, 2018; Published online April 20, 2018
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utb.fulltext.sponsorship This work was financially supported by the Czech Science Foundation (No. 17-16928Y) and by the Ministry of Education, Youth and Sports of the Czech Republic within the NPU I programme (No. LO1504).
utb.wos.affiliation [Jandikova, Gabriela; Stoplova, Petra; Di Martino, Antonio; Stloukal, Petr; Kucharczyk, Pavel; Machovsky, Michal; Sedlarik, Vladimir] Tomas Bata Univ Zlin, Univ Inst, Ctr Polymer Syst, Tr Tomas Bati 5678, Zlin 76001, Czech Republic
utb.scopus.affiliation Centre of Polymer Systems, University Institute, Tomas Bata University in Zlin, tr. Tomas Bati 5678, Zlin, Czech Republic
utb.fulltext.projects 17-16928Y
utb.fulltext.projects LO1504
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