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Mathematical model of the bleaching process with chemical kinetics of first and general order

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dc.title Mathematical model of the bleaching process with chemical kinetics of first and general order en
dc.contributor.author Beltrán-Prieto, Juan Carlos
dc.contributor.author Kolomazník, Karel
dc.relation.ispartof Reaction Kinetics, Mechanisms and Catalysis
dc.identifier.issn 1878-5190 Scopus Sources, Sherpa/RoMEO, JCR
dc.date.issued 2018
utb.relation.volume 123
utb.relation.issue 2
dc.citation.spage 485
dc.citation.epage 503
dc.type article
dc.language.iso en
dc.publisher Springer Netherlands
dc.identifier.doi 10.1007/s11144-017-1338-0
dc.relation.uri https://link.springer.com/article/10.1007/s11144-017-1338-0
dc.subject Diffusion en
dc.subject Efficiency factor en
dc.subject Difference finite method en
dc.subject Boundary conditions en
dc.subject Perturbation method en
dc.description.abstract Mathematical modeling of the bleaching process with a chemical reaction and diffusion of bleaching agent into a thin polymeric matrix film by movement through the micropores is studied in the present paper. The model was developed after considering theoretical methods of chemical engineering, the physical operation mechanism of the bleaching process and the main parameters that influence the diffusion mechanism. The efficiency factor for chemical kinetics of first and nth order processes were described using analytical solutions and perturbation methods. For the solution of the dynamic model, two cases of boundary conditions were explored. The first case describes diffusion in a well-stirred medium and the second case describes the situation when the bulk fluid moves slowly and interfacial resistance is present. In the latter case, the difference finite method was used as numerical tool for solving the problem and finding the concentration profile in the direction of the x-axis. Accordingly, experimental measurements were performed to determine the effective diffusion coefficient of bleaching agent in a polymeric matrix. © 2017, Akadémiai Kiadó, Budapest, Hungary. en
utb.faculty Faculty of Applied Informatics
dc.identifier.uri http://hdl.handle.net/10563/1007790
utb.identifier.obdid 43878644
utb.identifier.scopus 2-s2.0-85039862616
utb.identifier.wok 000426807200014
utb.source j-scopus
dc.date.accessioned 2018-04-23T15:01:44Z
dc.date.available 2018-04-23T15:01:44Z
dc.description.sponsorship MEYS, Ministry of Education, Youth and Science; MSMT-7778/2014, National Landcare Programme; LO1303, National Landcare Programme
dc.description.sponsorship Ministry of Education, Youth and Sports of the Czech Republic within the National Sustainability Programme Project [LO1303 (MSMT-7778/2014)]
utb.ou CEBIA-Tech
utb.contributor.internalauthor Beltrán-Prieto, Juan Carlos
utb.contributor.internalauthor Kolomazník, Karel
utb.fulltext.affiliation Juan Carlos Beltrán-Prieto1 • Karel Kolomazník1 ✉ Juan Carlos Beltrán-Prieto prieto@fai.utb.cz 1 Faculty of Applied Informatics, Tomas Bata University in Zlín, nám. T. G. Masaryka 5555, 760 01 Zlín, Czech Republic
utb.fulltext.dates Received: 19 October 2017 / Accepted: 17 December 2017 / Published online: 27 December 2017
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utb.fulltext.sponsorship This work was supported by the Ministry of Education, Youth and Sports of the Czech Republic within the National Sustainability Programme Project No. LO1303 (MSMT-7778/2014).
utb.scopus.affiliation Faculty of Applied Informatics, Tomas Bata University in Zlín, nám. T. G. Masaryka 5555, Zlín, Czech Republic
utb.fulltext.projects LO1303 (MSMT-7778/2014)
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