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Molybdenum and tungsten disulfides surface-modified with a conducting polymer, polyaniline, for application in electrorheology

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dc.title Molybdenum and tungsten disulfides surface-modified with a conducting polymer, polyaniline, for application in electrorheology en
dc.contributor.author Stejskal, Jaroslav
dc.contributor.author Mrlík, Miroslav
dc.contributor.author Plachý, Tomáš
dc.contributor.author Trchová, Miroslava
dc.contributor.author Kovářová, Jana
dc.contributor.author Li, Yu
dc.relation.ispartof Reactive and Functional Polymers
dc.identifier.issn 1381-5148 Scopus Sources, Sherpa/RoMEO, JCR
dc.date.issued 2017
utb.relation.volume 120
dc.citation.spage 30
dc.citation.epage 37
dc.type article
dc.language.iso en
dc.publisher Elsevier
dc.identifier.doi 10.1016/j.reactfunctpolym.2017.09.004
dc.relation.uri https://www.sciencedirect.com/science/article/pii/S1381514817301748
dc.subject Conducting polymer en
dc.subject Conductivity en
dc.subject Electrorheology en
dc.subject MoS2 en
dc.subject Polyaniline en
dc.subject WS2 en
dc.description.abstract Molybdenum and tungsten sulfides are semiconducting materials with flake-like morphology. Their applicability in electrorheological suspensions was enabled by the coating with a conducting polymer, polyaniline, after its conversion to non-conducting polyaniline base. For instance, the conductivity of tungsten sulfide, 0.056 S cm−1, increased to 0.98 S cm−1 after coating with polyaniline, and was conveniently reduced to 6.3 × 10−6 S cm−1 after conversion to polyaniline base. Such approach reduces the potential current drifts in electrorheological suspensions and allows for the application of sulfides in electrorheology. The optical microscopy demonstrated the formation of particle chains in silicone-oil suspensions after application of electric field. The electrorheological performance was assessed by the measurement of viscosity on the shear rate in the absence and in the presence of electric field and it is discussed on the bases of dielectric spectra. © 2017 Elsevier B.V. en
utb.faculty University Institute
dc.identifier.uri http://hdl.handle.net/10563/1007496
utb.identifier.obdid 43877164
utb.identifier.scopus 2-s2.0-85029604758
utb.identifier.wok 000413883800004
utb.identifier.coden RFPOF
utb.source j-scopus
dc.date.accessioned 2017-10-16T14:43:39Z
dc.date.available 2017-10-16T14:43:39Z
dc.description.sponsorship 17-04109S, GACR, Grantová Agentura České Republiky; LO1504, MŠMT, Ministerstvo Školství, Mládeže a Tělovýchovy
dc.description.sponsorship Czech Science Foundation [17-04109S]; Ministry of Education, Youth and Sports of the Czech Republic (NPU I) [LO1504]
utb.ou Centre of Polymer Systems
utb.contributor.internalauthor Mrlík, Miroslav
utb.contributor.internalauthor Plachý, Tomáš
utb.fulltext.affiliation Jaroslav Stejskal a,⁎ , Miroslav Mrlík b , Tomáš Plachý b , Miroslava Trchová a , Jana Kovářová a , Yu Li a,c a Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, 162 06 Prague 6, Czech Republic b Centre of Polymer Systems, Tomas Bata University in Zlin, 760 01 Zlin, Czech Republic c Department of Applied Chemistry, School of Science, Xi'an Jiaotong University, Xi'an 710049, People's Republic of China ⁎ Corresponding author. E-mail address: stejskal@imc.cas.cz (J. Stejskal).
utb.fulltext.dates Received 2 August 2017 Received in revised form 30 August 2017 Accepted 14 September 2017 Available online 18 September 2017
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utb.fulltext.sponsorship The authors thank the Czech Science Foundation (17-04109S) for financial support. M.M. and T.P. gratefully acknowledge the support of the Ministry of Education, Youth and Sports of the Czech Republic (NPU I, LO1504).
utb.scopus.affiliation Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, Prague 6, Czech Republic; Centre of Polymer Systems, Tomas Bata University in Zlin, Zlin, Czech Republic; Department of Applied Chemistry, School of Science, Xi'an Jiaotong University, Xi'an, China
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