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The power of non-hydrolytic sol-gel chemistry: A review

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dc.title The power of non-hydrolytic sol-gel chemistry: A review en
dc.contributor.author Stýskalík, Aleš
dc.contributor.author Škoda, David
dc.contributor.author Barnes, Craig E.
dc.contributor.author Pinkas, Jiří
dc.relation.ispartof Catalysts
dc.identifier.issn 2073-4344 Scopus Sources, Sherpa/RoMEO, JCR
dc.date.issued 2017
utb.relation.volume 7
utb.relation.issue 6
dc.type review
dc.language.iso en
dc.publisher Molecular Diversity Preservation International (MDPI)
dc.identifier.doi 10.3390/catal7060168
dc.relation.uri http://www.mdpi.com/2073-4344/7/6/168/htm
dc.subject non-hydrolytic en
dc.subject sol-gel en
dc.subject non-aqueous en
dc.subject metal oxides en
dc.subject porosity en
dc.description.abstract This review is devoted to non-hydrolytic sol-gel chemistry. During the last 25 years, non-hydrolytic sol-gel (NHSG) techniques were found to be attractive and versatile methods for the preparation of oxide materials. Compared to conventional hydrolytic approaches, the NHSG route allows reaction control at the atomic scale resulting in homogeneous and well defined products. Due to these features and the ability to design specific materials, the products of NHSG reactions have been used in many fields of application. The aim of this review is to present an overview of NHSG research in recent years with an emphasis on the syntheses of mixed oxides, silicates and phosphates. The first part of the review highlights well known condensation reactions with some deeper insights into their mechanism and also presents novel condensation reactions established in NHSG chemistry in recent years. In the second section we discuss porosity control and novel compositions of selected materials. In the last part, the applications of NHSG derived materials as heterogeneous catalysts and supports, luminescent materials and electrode materials in Li-ion batteries are described. © 2017 by the authors. Licensee MDPI, Basel, Switzerland. en
utb.faculty University Institute
dc.identifier.uri http://hdl.handle.net/10563/1007429
utb.identifier.obdid 43876461
utb.identifier.scopus 2-s2.0-85020472300
utb.identifier.wok 000404380300002
utb.source j-scopus
dc.date.accessioned 2017-09-08T12:14:55Z
dc.date.available 2017-09-08T12:14:55Z
dc.description.sponsorship LO1504, MŠMT, Ministerstvo Školství, Mládeže a Tělovýchovy; LQ1601, MŠMT, Ministerstvo Školství, Mládeže a Tělovýchovy
dc.description.sponsorship Ministry of Education, Youth and Sports of the Czech Republic under the project CEITEC [LQ1601]; Ministry of Education, Youth and Sports of the Czech Republic under Program NPU I [LO1504]; Center for Direct Catalytic Conversion of Biomass to Biofuels (C3Bio); Energy Frontier Research Center - U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DESC0000997]; DOE BES [DE-FG02-01ER15259]
dc.rights Attribution 4.0 International
dc.rights.uri http://creativecommons.org/licenses/by/4.0/
dc.rights.access openAccess
utb.ou Centre of Polymer Systems
utb.contributor.internalauthor Škoda, David
utb.scopus.affiliation Department of Chemistry, Masaryk University, Kotlarska 2, Brno, Czech Republic; CEITEC MU, Masaryk University, Kamenice 5, Brno, Czech Republic; Department of Chemistry, University of Tennessee, Knoxville, TN, United States; Centre of Polymer Systems, Tomas Bata University in Zlin, Tr. T. Bati 5678, Zlin, Czech Republic
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