Microporous conjugated polymers via homopolymerization of 2,5-diethynylthiophene

Bondarev, Dmitrij; Sivkova, Radoslava; Šuly, Pavol; Polášková, Martina; Krejčí, Ondřej; Křikavová, Radka; Trávníček, Zdeněk; Zukal, Arnošt; Kubů, Martin; Sedláček, Jan

dc.title	Microporous conjugated polymers via homopolymerization of 2,5-diethynylthiophene	en
dc.contributor.author	Bondarev, Dmitrij
dc.contributor.author	Sivkova, Radoslava
dc.contributor.author	Šuly, Pavol
dc.contributor.author	Polášková, Martina
dc.contributor.author	Krejčí, Ondřej
dc.contributor.author	Křikavová, Radka
dc.contributor.author	Trávníček, Zdeněk
dc.contributor.author	Zukal, Arnošt
dc.contributor.author	Kubů, Martin
dc.contributor.author	Sedláček, Jan
dc.relation.ispartof	European Polymer Journal
dc.identifier.issn	0014-3057 Scopus Sources, Sherpa/RoMEO, JCR
dc.date.issued	2017
utb.relation.volume	92
dc.citation.spage	213
dc.citation.epage	219
dc.type	article
dc.language.iso	en
dc.publisher	Elsevier
dc.identifier.doi	10.1016/j.eurpolymj.2017.04.042
dc.relation.uri	https://www.sciencedirect.com/science/article/pii/S0014305717300162
dc.subject	Thiophene	en
dc.subject	Microporous	en
dc.subject	Catalysis	en
dc.subject	Polymerization	en
dc.subject	Conjugated polymer	en
dc.subject	Adsorption	en
dc.description.abstract	Homopolymerizations of 2,5-diethynylthiophene into conjugated microporous polymers by (i) chain-growth polymerization and (ii) polycyclotrimerization are described. Both methods provide nearly quantitative yields of thiophene-rich (7.6 mmol thiophene rings/g) networks with specific surface area up to 839 m2/g. The thiophene units enhance the affinity of the networks to CO2 and red-shift the UV/vis and fluorescence absorption and emission bands of the networks, respectively. © 2017 Elsevier Ltd	en
utb.faculty	University Institute
dc.identifier.uri	http://hdl.handle.net/10563/1007349
utb.identifier.obdid	43876694
utb.identifier.scopus	2-s2.0-85019182165
utb.identifier.wok	000404315600020
utb.identifier.coden	EUPJA
utb.source	j-scopus
dc.date.accessioned	2017-09-08T12:14:43Z
dc.date.available	2017-09-08T12:14:43Z
dc.description.sponsorship	15-09637S, GACR, Grantová Agentura České Republiky
dc.description.sponsorship	Czech Science Foundation [15-09637S]; Ministry of Education, Youth and Sports [NPU I (LO1504)]; Slovak Research and Development Agency APVV [APVV-15-0545]
utb.ou	Centre of Polymer Systems
utb.contributor.internalauthor	Šuly, Pavol
utb.contributor.internalauthor	Polášková, Martina
utb.contributor.internalauthor	Krejčí, Ondřej
utb.fulltext.affiliation	Dmitrij Bondarev a⁎, Radoslava Sivkova b,c, Pavol Šuly d, Martina Polášková e, Ondřej Krejčí e, Radka Křikavová f, Zdeněk Trávníček f, Arnošt Zukal g, Martin Kubů g, Jan Sedláček b⁎ a Polymer Institute, Slovak Academy of Science, Dúbravská cesta 9, 845 41 Bratislava, Slovakia b Department of Physical and Macromolecular Chemistry, Faculty of Science, Charles University in Prague, Hlavova 2030, CZ-128 43 Prague, Czech Republic c Department of Chemistry and Physics of Surfaces and Biointerfaces, Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, Heyrovsky Sq. 2, 162 06 Prague 6, Czech Republic d Centre of Polymer Systems, Tomas Bata University in Zlin, Tr. Tomase Bati 5678, CZ-76001 Zlín, Czech Republic e Department of Polymer Engineering, Faculty of Technology, Tomas Bata University in Zlin, Vavrečkova 275, CZ-762 72 Zlín, Czech Republic f Department of Inorganic Chemistry, Faculty of Science, Palacký University, 17. listopadu 12, 771 46 Olomouc, Czech Republic g J. Heyrovský Institute of Physical Chemistry, v.v.i., Academy of Sciences of the Czech Republic, Dolejškova 3, CZ-182 23 Prague 8, Czech Republic ⁎ Corresponding authors. E-mail addresses: dmitrij.bondarev@savba.sk (D. Bondarev), jansedl@natur.cuni.cz (J. Sedláček).
utb.fulltext.dates	Received 4 January 2017 Received in revised form 14 April 2017 Accepted 30 April 2017 Available online 02 May 2017
utb.fulltext.faculty	Faculty of Technology
utb.fulltext.faculty	Faculty of Technology
utb.fulltext.ou	Centre of Polymer Systems
utb.fulltext.ou	Department of Polymer Engineering
utb.fulltext.ou	Department of Polymer Engineering