Polyacrylamide brushes with varied morphologies as a tool for control of the intermolecular interactions within EPDM/MVQ blends

Galeziewska, Monika; Lipinska, Magdalena; Mrlík, Miroslav; Ilčíková, Markéta; Gajdošová, Veronika; Šlouf, Miroslav; Achbergerová, Eva; Musilová, Lenka; Mosnáček, Jaroslav; Pietrasik, Joanna

dc.title	Polyacrylamide brushes with varied morphologies as a tool for control of the intermolecular interactions within EPDM/MVQ blends	en
dc.contributor.author	Galeziewska, Monika
dc.contributor.author	Lipinska, Magdalena
dc.contributor.author	Mrlík, Miroslav
dc.contributor.author	Ilčíková, Markéta
dc.contributor.author	Gajdošová, Veronika
dc.contributor.author	Šlouf, Miroslav
dc.contributor.author	Achbergerová, Eva
dc.contributor.author	Musilová, Lenka
dc.contributor.author	Mosnáček, Jaroslav
dc.contributor.author	Pietrasik, Joanna
dc.relation.ispartof	Polymer
dc.identifier.issn	0032-3861 Scopus Sources, Sherpa/RoMEO, JCR
dc.date.issued	2021
utb.relation.volume	215
dc.type	article
dc.language.iso	en
dc.publisher	Elsevier Ltd
dc.identifier.doi	10.1016/j.polymer.2021.123387
dc.relation.uri	https://www.sciencedirect.com/science/article/pii/S0032386121000100
dc.subject	polymer brushes	en
dc.subject	polyacrylamide	en
dc.subject	montmorillonite	en
dc.subject	polymer blends	en
dc.subject	compatibilizers	en
dc.description.abstract	The specific interactions between polyacrylamide brushes composed of polyacrylamide chains tethered to montmorillonite particles (Mt-g-PAm) and the individual components of immiscible ethylene-propylene-diene modified with sorbic acid (EPDM) and methyl vinyl silicone (MVQ) blends were studied. The effect of various lengths of PAm chains and their grafting density on montmorillonite (Mt) surface was investigated. It was determined that, due to interactions generated within the system through carboxyl and amide groups the brush particles were selectively located at the EPDM/MVQ interphase and in the EPDM phase. Furthermore, the longer PAm chains resulted in an increase of the glass transition of EPDM, unification of blend morphology, and the reduction of crystallinity of the MVQ phase. Therefore, precisely designed polymer brushes could be considered as novel functional compatibilizers, that provide a new tool for the future material designing. © 2021 Elsevier Ltd	en
utb.faculty	University Institute
utb.faculty	Faculty of Applied Informatics
utb.faculty	Faculty of Technology
dc.identifier.uri	http://hdl.handle.net/10563/1010180
utb.identifier.obdid	43882450
utb.identifier.scopus	2-s2.0-85099380921
utb.identifier.wok	000618221800001
utb.identifier.coden	POLMA
utb.source	j-scopus
dc.date.accessioned	2021-01-26T12:12:57Z
dc.date.available	2021-01-26T12:12:57Z
dc.description.sponsorship	National Science Centre, PolandNational Science Center, PolandNational Science Centre, Poland [UMO-2016/23/P/ST5/02131]; European UnionEuropean Commission [665778]; Ministry of Education, Youth and Sports of the Czech republic -DKRVO [RP/CPS/2020/003]; Research & Innovation Operational Programme - ERDF [313021T081]; [VEGA 2/0129/19]; [APVV-19-0338]
dc.description.sponsorship	665778; UMO-2016/23/P/ST5/02131; Slovenská Akadémia Vied, SAV: 313021T081; Ministerstvo Školství, Mládeže a Tělovýchovy, MŠMT: RP/CPS/2020/003; Narodowe Centrum Nauki, NCN; European Regional Development Fund, FEDER: APVV-19-0338, VEGA 2/0129/19
utb.ou	Centre of Polymer Systems
utb.ou	CEBIA-Tech
utb.ou	Department of Physics and Materials Engineering
utb.contributor.internalauthor	Mrlík, Miroslav
utb.contributor.internalauthor	Achbergerová, Eva
utb.contributor.internalauthor	Musilová, Lenka
utb.fulltext.affiliation	Monika Galeziewska a, Magdalena Lipinska a, Miroslav Mrlik b, Marketa Ilcikova a,c, Veronika Gajdosova d, Miroslav Slouf d, Eva Achbergerová e, Lenka Musilová f, Jaroslav Mosnacek c,g, Joanna Pietrasik a a Lodz University of Technology, Department of Chemistry, Institute of Polymer and Dye Technology, Stefanowskiego 12/16, 90 924, Lodz, Poland b Tomas Bata University in Zlin, University Institute, Centre of Polymer Systems, Trida T. Bati 5678, Zlin, 76001, Czech Republic c Polymer Institute, Slovak Academy of Sciences, Dubravska Cesta 9, 845 41, Bratislava, Slovakia d Institute of Macromolecular Chemistry, Czech Academy of Sciences, Heyrovskeho Namesti 2, 162 06, Praha 6, Czech Republic e CEBIA-Tech, Faculty of Applied Informatics, Tomas Bata University in Zlín, Nad Stráněmi 4511, 760 05, Zlín, Czech Republic f Department of Physics and Materials Engineering, Faculty of Technology, Tomas Bata University in Zlin, Vavrečkova 5569, 760 01, Zlín, Czech Republic g Centre for Advanced Materials Application, Slovak Academy of Sciences, Dubravska Cesta 9, 845 11, Bratislava, Slovakia
utb.fulltext.dates	Received 19 October 2020 Revised 2 January 2021 Accepted 6 January 2021 Available online 11 January 2021
utb.fulltext.sponsorship	The authors thank to National Science Centre, Poland for the financial support through POLONEZ ( UMO-2016/23/P/ST5/02131 ) which has received funding from the European Unions's Horizon 2020 research and innovation program under Marie Sklodowska-Curie grant agreement. No 665778 . This work was supported by the Ministry of Education, Youth and Sports of the Czech republic - DKRVO ( RP/CPS/2020/003 ). This study was also performed during the implementation of the project Building-up Centre for advanced materials application of the Slovak Academy of Sciences, ITMS project code 313021T081 supported by Research & Innovation Operational Programme funded by the ERDF. JM acknowledges for financial support to project VEGA 2/0129/19. MI and JM acknowledge APVV-19-0338.
utb.wos.affiliation	[Galeziewska, Monika; Lipinska, Magdalena; Ilcikova, Marketa; Pietrasik, Joanna] Lodz Univ Technol, Inst Polymer & Dye Technol, Dept Chem, Stefanowskiego 12-16, PL-90924 Lodz, Poland; [Mrlik, Miroslav] Tomas Bata Univ Zlin, Univ Inst, Ctr Polymer Syst, Trida T Bati 5678, Zlin 76001, Czech Republic; [Ilcikova, Marketa; Mosnacek, Jaroslav] Slovak Acad Sci, Polymer Inst, Dubravska Cesta 9, Bratislava 84541, Slovakia; [Gajdosova, Veronika; Slouf, Miroslav] Czech Acad Sci, Inst Macromol Chem, Heyrovskeho Namesti 2, Prague 16206 6, Czech Republic; [Achbergerova, Eva] Tomas Bata Univ Zlin, Fac Appl Informat, CEBIA Tech, Stranemi 4511, Zlin 76005, Czech Republic; [Musilova, Lenka] Tomas Bata Univ Zlin, Fac Technol, Dept Phys & Mat Engn, Vavreckova 5569, Zlin 76001, Czech Republic; [Mosnacek, Jaroslav] Slovak Acad Sci, Ctr Adv Mat Applicat, Dubravska Cesta 9, Bratislava 84511, Slovakia
utb.scopus.affiliation	Lodz University of Technology, Department of Chemistry, Institute of Polymer and Dye Technology, Stefanowskiego 12/16, Lodz, 90 924, Poland; Tomas Bata University in Zlin, University Institute, Centre of Polymer Systems, Trida T. Bati 5678, Zlin, 76001, Czech Republic; Polymer Institute, Slovak Academy of Sciences, Dubravska Cesta 9, Bratislava, 845 41, Slovakia; Institute of Macromolecular Chemistry, Czech Academy of Sciences, Heyrovskeho Namesti 2, Praha 6, 162 06, Czech Republic; CEBIA-Tech, Faculty of Applied Informatics, Tomas Bata University in Zlín, Nad Stráněmi 4511, Zlín, 760 05, Czech Republic; Department of Physics and Materials Engineering, Faculty of Technology, Tomas Bata University in Zlin, Vavrečkova 5569, Zlín, 760 01, Czech Republic; Centre for Advanced Materials Application, Slovak Academy of Sciences, Dubravska Cesta 9, Bratislava, 845 11, Slovakia
utb.fulltext.projects	UMO-2016/23/P/ST5/02131
utb.fulltext.projects	Horizon 2020
utb.fulltext.projects	665778
utb.fulltext.projects	RP/CPS/2020/003
utb.fulltext.projects	313021T081
utb.fulltext.projects	VEGA 2/0129/19
utb.fulltext.projects	APVV-19-0338
utb.fulltext.faculty	University Institute
utb.fulltext.faculty	Faculty of Applied Informatics
utb.fulltext.faculty	Faculty of Technology
utb.fulltext.ou	Centre of Polymer Systems
utb.fulltext.ou	CEBIA-Tech
utb.fulltext.ou	Department of Physics and Materials Engineering