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Název: | A facile prestrain-stick-release assembly of stretchable supercapacitors based on highly stretchable and sticky hydrogel electrolyte | ||||||||||
Autor: | Tang, Qianqiu; Chen, Mingming; Wang, Gengchao; Bao, Hua; Sáha, Petr | ||||||||||
Typ dokumentu: | Recenzovaný odborný článek (English) | ||||||||||
Zdrojový dok.: | Journal of Power Sources. 2015, vol. 284, p. 400-408 | ||||||||||
ISSN: | 0378-7753 (Sherpa/RoMEO, JCR) | ||||||||||
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DOI: | https://doi.org/10.1016/j.jpowsour.2015.03.059 | ||||||||||
Abstrakt: | A facile prestrain-stick-release assembly strategy for the stretchable supercapacitor device is developed based on a novel Na2SO4-aPUA/PAAM hydrogel electrolyte, saving the stretchable rubber base conventionally used. The Na2SO4-aPUA/PAAM hydrogel electrolyte exhibits high stretchability (>1000%), electrical conductivity (0.036 S cm-1) and stickiness. Due to the unique features of the hydrogel electrolyte, the carbon nanotube@MnO2 film electrodes can be firmly stuck to two sides of the prestrained hydrogel electrolyte. Then, by releasing the hydrogel electrolyte, homogenous buckles are formed for the film electrodes to get a full stretchable supercapacitor device. Besides, the high stickiness of the hydrogel electrolyte ensures its strong adhesion with the film electrodes, facilitating ion and electronic transfer of the supercapacitor. As a result, excellent electrochemical performance is achieved with the specific capacitance of 478.6 mF cm-2 at 0.5 mA cm-2 (corresponding to 201.1 F g-1) and capacitance retention of 91.5% after 3000 charging-discharging cycles under 150% strain, which is the best for the stretchable supercapacitors. © 2015 Elsevier B.V. All rights reserved. | ||||||||||
Plný text: | https://www.sciencedirect.com/science/article/pii/S0378775315004759 | ||||||||||
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