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| dc.title | Time-resolved study of the photo-curing process of dental resins with the NMR-MOUSE | en |
| dc.contributor.author | Marchi Netto, Antonio | |
| dc.contributor.author | Steinhaus, Johannes | |
| dc.contributor.author | Hausnerová, Berenika | |
| dc.contributor.author | Moeginger, Bernhard | |
| dc.contributor.author | Blümich, Bernhard | |
| dc.relation.ispartof | Applied Magnetic Resonance | |
| dc.identifier.issn | 0937-9347 Scopus Sources, Sherpa/RoMEO, JCR | |
| dc.date.issued | 2013 | |
| utb.relation.volume | 44 | |
| utb.relation.issue | 9 | |
| dc.citation.spage | 1027 | |
| dc.citation.epage | 1039 | |
| dc.type | article | |
| dc.language.iso | en | |
| dc.publisher | Springer Wien | en |
| dc.identifier.doi | 10.1007/s00723-013-0458-6 | |
| dc.relation.uri | https://link.springer.com/article/10.1007/s00723-013-0458-6 | |
| dc.description.abstract | The photo-curing reaction of dental resins has been examined with unilateral nuclear magnetic resonance (NMR-MOUSE) allowing nondestructive high-resolution measurement of depth profiles as a function of time and space. The NMR signal is sensitive to both the monomer concentration and changes in molecular mobility. Upon irradiation with blue light, it first increases due to molecular mobility enhanced by the reaction heat and then decreases exponentially with the monomer concentration as the polymer signal is lost in the dead time of the instrument upon curing. The space and time dependence of the NMR signal can be described by the photo-polymerization reaction kinetics together with a heuristic approximation of the temperature dependence. © 2013 Springer-Verlag Wien. | en |
| utb.faculty | Faculty of Technology | |
| dc.identifier.uri | http://hdl.handle.net/10563/1003442 | |
| utb.identifier.obdid | 43870190 | |
| utb.identifier.scopus | 2-s2.0-84881052467 | |
| utb.identifier.wok | 000322648200004 | |
| utb.identifier.coden | APMRE | |
| utb.source | j-scopus | |
| dc.date.accessioned | 2013-08-21T10:18:12Z | |
| dc.date.available | 2013-08-21T10:18:12Z | |
| dc.rights.access | openAccess | |
| utb.contributor.internalauthor | Steinhaus, Johannes | |
| utb.contributor.internalauthor | Hausnerová, Berenika | |
| utb.scopus.affiliation | Marchi Netto A., Institut für Technische und Makromolekulare Chemie, RWTH Aachen University, 52074 Aachen, Worringerweg 1, Germany; Steinhaus J., Centre of Polymer Systems, Department of Production Engineering, Tomas Bata University in Zlín, Zlín, Czech Republic, Department of Natural Sciences, Bonn-Rhein-Sieg University of Applied Sciences, Rheinbach, Germany; Hausnerova B., Centre of Polymer Systems, Department of Production Engineering, Tomas Bata University in Zlín, Zlín, Czech Republic; Moeginger B., Department of Natural Sciences, Bonn-Rhein-Sieg University of Applied Sciences, Rheinbach, Germany; Blümich B., Institut für Technische und Makromolekulare Chemie, RWTH Aachen University, 52074 Aachen, Worringerweg 1, Germany |