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dc.title | Krystalizace a transformace polybutenu-1 | cs |
dc.title | Crystalization and transformation of polybutene-1 | en |
dc.contributor.author | Kaszonyiová, Martina | |
dc.contributor.author | Rybnikář, František | |
dc.contributor.author | Geil, Phillip H. | |
dc.relation.ispartof | Journal of Macromolecular Science, Part B: Physics | |
dc.identifier.issn | 0022-2348 Scopus Sources, Sherpa/RoMEO, JCR | |
dc.date.issued | 2004 | |
utb.relation.volume | 43 | |
utb.relation.issue | 5 | |
dc.citation.spage | 1095 | |
dc.citation.epage | 1114 | |
dc.type | article | |
dc.language.iso | en | |
dc.publisher | Taylor & Francis Inc. | en |
dc.identifier.doi | 10.1081/MB-200033322 | |
dc.relation.uri | https://www.tandfonline.com/doi/full/10.1081/MB-200033322 | |
dc.relation.uri | https://www.tandfonline.com/doi/pdf/10.1081/MB-200033322 | |
dc.subject | Isotermální krystalizace | cs |
dc.subject | rtg- diffrakce | cs |
dc.subject | Isoterrmal crystalization | en |
dc.subject | sodium salicilate | en |
dc.subject | talc | en |
dc.subject | X-ray diffraction | en |
dc.description.abstract | Isotermní krystalizace a fázová II- I transformace za různých teplot byla zkoumána RTG difrakcí. Krystalizační rychlost může být zvýšenáa přidáním různých pevných látek jako salicilan sodný a mastek, kterí např. zvyšují rychlost víc než 100% a nebo snižují víc než 300%. | cs |
dc.description.abstract | The isothermal crystallization and phase II # I transformation of bulk polybutene-1 at various temperatures has been characterized by X-ray diffraction. The crystallization rate can be increased or decreased by the addition of various solids, with sodium salicylate and talc, e.g., increasing the rate by >100% and decreasing the rate by >300%, respectively. The nucleating agents have no effect on the transformation rate, which is, however, increased slightly in the presence of water and ethanol and significantly in the presence of liquids which are solvents at elevated temperatures or by the application of tension, compression or temperature cycling. The transformation rate of non-treated polymer is greatest near 25 °C, decreasing at higher and lower temperatures. | en |
utb.faculty | Faculty of Technology | |
dc.identifier.uri | http://hdl.handle.net/10563/1000357 | |
utb.identifier.rivid | RIV/70883521:28110/04:63502540 | |
utb.identifier.obdid | 12052808 | |
utb.identifier.scopus | 2-s2.0-5744250325 | |
utb.identifier.wok | 000224162700015 | |
utb.source | j-riv | |
utb.contributor.internalauthor | Kaszonyiová, Martina | |
utb.contributor.internalauthor | Rybnikář, František | |
utb.fulltext.affiliation | M. Kaszonyiova,1 F. Rybnikar,1,* and P. H. Geil1,2 1 Department of Polymer Material and Technology, University of Thomas Bata, Zlin, Czech Republic 2 Department of Materials Science and Engineering, University of Illinois, Urbana, Illinois, USA *Correspondence: F. Rybnikar, Department of Polymer Material and Technology, University of Thomas Bata, Zlin 76001, Czech Republic; E-mail: rybnikar@ft.utb.cz | |
utb.fulltext.dates | Received May 2, 2003 Accepted April 28, 2003 | |
utb.fulltext.references | 1. Geil, P.H. Polymer Single Crystals; Interscience: New York, 1963, 427. 2. Turner-Jones, A. J. Polym. Sci. Part B 1963, 1, 455. 3. Natta, G.; Corradini, P.; Bassi, I.W. Makromol. Chem. 1957, 21, 240. 4. Holland, V.F.; Miller, R.L. J. Appl. Phys. 1964, 35, 3241. 5. Goldbach, G.; Peitscher, G. J. Polym. Sci. 1986, B6, 783. 6. Armeniades, C.D.; Baer, E. J. Macromol. Sci. Phys. 1967, B1, 309. 7. Kopp, S.; Whitmann, J.C.; Lotz, B. Polymer 1994, 35, 908. 8. Kopp, S.; Whitmann, J.C.; Lotz, B. Polymer 1994, 35, 916. 9. Zannetti, R.; Manarersi, P.; Buzzoni, G.C. Chim. Ind. 1961, 43, 735. 10. Danuso, F.; Gianotti, G. Makromol. Chem. 1963, 61, 139. 11. Cojazzi, G.; Malta, V.; Cellotti, G.; Zanneti, R. Makromol. Chem. 1976, 177, 915. 12. Chau, K.W.; Yang, Y.C.; Geil, P.H. J. Mater. Sci. 1986, 21, 3002. 13. Icenogle, R.D. J. Polym. Sci. 1985, 23, 1369. 14. Hsu, T.C.; Geil, P.H. J. Macromol. Sci. Phys. 1989, B28, 69. 15. Fujiwara, Y. Polym. Bull. 1985, 13, 253. 16. Kopp, S.; Wittmann, J.C.; Lotz, B. J. Mater. Sci. 1994, 29, 6159. 17. Chau, K.W.; Geil, P.H. J. Macromol. Sci. Phys. 1984, B23, 115. 18. Rybnikar, F. J. Appl. Polym. Sci. 1985, 30, 1949. 19. Kaszonyiova, M.; Rybnikar, F. (to be published). 20. Carr, S.H.; Keller, A.; Baer, E. J. Polym. Sci. A-2 1970, 4, 1467. 21. Morgan, L.B. Phil. Trans. Royal Soc. (Lond.) 1954, A297, 13. 22. Hsu, C.C.; Geil, P.H. J. Macromol. Sci. Phys. 1986, B25, 433. 23. Oda, T.; Maeda, M.; Hibi, S.; Watanabe, S. Kobunshi Ronbushu, Eng. Ed. 1974, 3, 189. 24. Weynant, E.; Haudin, J.C.; Sell, C.G. J. Mater. Sci. 1982, 17, 1017. 25. Petraccone, V.; Pirozzi, B.; Frasca, A.; Corradini, P. Eur. Polym. J. 1976, 12, 323. 26. Tadokoro, H. Structure of Crystalline Polymers; Wiley-Interscience: New York, 1976; 356. 27. Hsu, T.C.; Geil, P.H. Polym. Commun. 1990, 31, 105. | |
utb.fulltext.sponsorship | This research was supported, in part, by Grant ME-131 from the Granting Agency of the Czech Republic and Grant DMR 0234678 from the Polymer and International Programs sections of the US, National Science Foundation. Appreciation is expressed to Prof. B. Lotz, University of Strasbourg, for numerous helpful comments. | |
utb.fulltext.projects | GACR ME-131 | |
utb.fulltext.projects | DMR 0234678 | |
utb.fulltext.faculty | Faculty of Technology | |
utb.fulltext.ou | Department of Polymer Material and Technology |