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dc.title | Biodegradation of technical mixtures of oxyethylenated aliphatic alcohols in an aqueous environment | en |
dc.contributor.author | Řezníčková, Iveta | |
dc.contributor.author | Hoffmann, Jaromír | |
dc.contributor.author | Komárek, K. | |
dc.relation.ispartof | Chemosphere | |
dc.identifier.issn | 0045-6535 Scopus Sources, Sherpa/RoMEO, JCR | |
dc.date.issued | 2002 | |
utb.relation.volume | 48 | |
utb.relation.issue | 1 | |
dc.citation.spage | 83 | |
dc.citation.epage | 87 | |
dc.type | article | |
dc.language.iso | en | |
dc.publisher | Pergamon Elsevier Science Ltd. | en |
dc.identifier.doi | 10.1016/S0045-6535(02)00039-5 | |
dc.relation.uri | https://www.sciencedirect.com/science/article/pii/S0045653502000395 | |
dc.subject | neinogenní tenzidy | cs |
dc.subject | biodegradace | cs |
dc.subject | oxyethylenované alkoholy | cs |
dc.subject | n-butylalkohol | cs |
dc.subject | iso-butylalkohol | cs |
dc.subject | n-pentylalkohol | cs |
dc.subject | iso-pentylalkohol | cs |
dc.subject | ethylenglykol | cs |
dc.subject | meziprodukty | cs |
dc.subject | Zahn-Wellens | cs |
dc.subject | nonionogenic surfactants | en |
dc.subject | biodegradation | en |
dc.subject | oxyethylenated alcohols | en |
dc.subject | n-butyl alcohol | en |
dc.subject | iso-butyl alcohol | en |
dc.subject | n-pentyl alcohol | en |
dc.subject | iso-pentyl alcohol | en |
dc.subject | ethylene glycols | en |
dc.subject | intermediates | en |
dc.subject | Zahn-Wellens nonionogenic surfactants | en |
dc.subject | biodegradation | en |
dc.subject | oxyethylenated alcohols | en |
dc.description.abstract | A study was conducted of the biodegradability of nonionogenic surfactants of oxyethylenated n-butyl, isobutyl, n-pentyl and isopentyl alcohol type by the modified static test according to ISO 9888. The course of degradation was judged by changes in concentration of individual oligomers, ethylene glycols, carboxylic and dicarboxylic acids. Good biological degradability of tested substrates was found, a "primary" degradability of 75% - 98% in a 10-day interval. Obtained results, in accord with our previous work, proved the dominant proportion of degradative scission in the hydrophile part of surfactant molecule. During biological degradation, no significant cumulation of mono- up to polyethylene glycols appeared neither that of mono- or dicarboxylic acids, and degradation of these components was not the rate-determining degradation factor. | en |
utb.faculty | Faculty of Technology | |
dc.identifier.uri | http://hdl.handle.net/10563/1000113 | |
utb.identifier.rivid | RIV/70883521:28110/02:63500568 | |
utb.identifier.obdid | 11052438 | |
utb.identifier.scopus | 2-s2.0-0036636329 | |
utb.identifier.wok | 000176576200011 | |
utb.source | j-riv | |
utb.contributor.internalauthor | Řezníčková, Iveta | |
utb.contributor.internalauthor | Hoffmann, Jaromír | |
utb.fulltext.affiliation | Iveta Řezníčková a, Jaromír Hoffmann a,*, Karel Komárek b a Faculty of Technology, Department of Environmental Technology and Chemistry, Tomas Bata University in Zlín, náměstí T.G. Masaryka 275, 762 72 Zlín, Czech Republic b Faculty of Chemical Technology, University of Pardubice, náměstí Čs. legií 565, 532 10 Pardubice, Czech Republic * Corresponding author. Tel.: +420-67-7541-209; fax: +420-67-7210-722. E-mail address: hoffmann@ft.utb.cz (J. Hoffmann). | |
utb.fulltext.dates | Received 30 May 2001; received in revised form 14 January 2002; accepted 21 January 2002 | |
utb.fulltext.references | Balson, T., Felix, M.S.B., 1995. Biodegrability of non-ionic surfactants. In: Carsa, D.R., Porter, M.R. (Eds.), Biodegrability of Surfactants. Balckie Academic & Professional, London. Corti, A., D’Antone, S., Solaro, R., Chiellini, E., 1998. Degradation of poly(ethylene glycol)-based nonionic surfactants by different bacterial isolates from river water. J. Env. Polym. Degrad. 6, 121–131. EN ISO standard 9888, 1999. Water quality––evaluation of ultimate aerobic biodegrability of organic compounds in aqueous medium. Static test (Zahn–Wellens method). Hoffmann, J., Komárek, K., Řezníčková, I., Richter, P., 1999. Biodegradation course of oxyethylenated medium alcohols in aqueous system. Toxicol. Environment. Chem. 72, 145–158. Kawai, F., 1994. In: Doi, Y., Fukuda, K. (Eds.), Biodegradable Plastics and Polymers. Elsevier, Amsterdam, pp. 24–38. Komárek, K., Kupec, J., Škvarenina, S., Pitthard, V., Hoffmann, J., Vaňková, S., Řezníčková, I., 1996. Biodegrability of oxyethylenatehd lower aliphatic alcohols in dependence on their structure. In: 3rd International Symposium Tocoen’96, Luhačovice, Czech republic, April 28–May 3, 1996. Kravetz, L., 1990. Biodegradation pathways of non-ionic ethoxylates. In: Glass, J.E., Swift, G. (Eds.), Agricultural and Synthetic Polymers Biodegradability and Utilization. ACS Symposium/Series, Washington, DC, pp. 96–109. Marcomini, A., Zanette, M., Pojana, G., Suter, M.F.J., 2000. Behavior of aliphatic alcohol polyethoxylates and their metabolites under standardized aerobic biodegradation conditions. Environ. Toxicol. Chem. 19, 549–554. Szymanski, A., Wyrvas, B., Swit, Z., Jaroszynski, T., Lukaszewski, Z., 2000. Biodegradation of fatty alcohol ethoxylates in the continuous flow activated sludge test. Water Res. 34, 4101–4109. White, G.F., 1993. Bacterial degradation of ethoxylated surfactants. Pesticide Sci. 37, 159–166. | |
utb.fulltext.sponsorship | This work was supported by the Research Project of the Ministry of Youth, Education and Sports of the Czech Republic No. MSM 281100002 and by the Grant Agency of the Czech Republic No. 104/95/0242. | |
utb.fulltext.projects | MSM 281100002 | |
utb.fulltext.projects | GACR 104/95/0242 |