Rheology of Poly(vinyl butyral) Solution Containing Fumed Silica in Correlation with Electrospinning

Peer, Petra; Polášková, Martina; Šuly, Pavol

dc.title	Rheology of Poly(vinyl butyral) Solution Containing Fumed Silica in Correlation with Electrospinning	en
dc.contributor.author	Peer, Petra
dc.contributor.author	Polášková, Martina
dc.contributor.author	Šuly, Pavol
dc.relation.ispartof	Chinese Journal of Polymer Science (English Edition)
dc.identifier.issn	0256-7679 Scopus Sources, Sherpa/RoMEO, JCR
dc.date.issued	2018
utb.relation.volume	36
utb.relation.issue	6
dc.citation.spage	742
dc.citation.epage	748
dc.type	article
dc.language.iso	en
dc.publisher	Springer Verlag
dc.identifier.doi	10.1007/s10118-018-2077-z
dc.relation.uri	https://link.springer.com/article/10.1007/s10118-018-2077-z
dc.subject	Electrospinning	en
dc.subject	Nanofibres	en
dc.subject	Poly(vinyl butyral)	en
dc.subject	Fumed silica	en
dc.subject	Rheology	en
dc.description.abstract	The rheological properties in question are influenced by many factors, ranging from the characteristics of the given polymer or solvent to the flowing conditions. The primary focus of this study is to analyse the rheological behaviour of poly(vinyl butyral)—Mowital B 60H—(PVB) solutions dissolved in methanol and a blend of these with fumed silica nanoparticles. The preparation of the nanofibrous web and the quality of nanofibres were correlated with the rheology of the polymer solution. It was discerned that drastically intensifying shear viscosity and the elasticity of the solution exerted a negligible effect on the formation of fibres, a finding which has rarely been discussed in the literature. The morphologies and structures of the PVB/silica nanofibrous membranes were investigated by scanning electron microscopy, thermogravimetric analysis and Fourier transform infrared spectroscopy. © 2018, Chinese Chemical Society, Institute of Chemistry, Chinese Academy of Sciences and Springer-Verlag GmbH Germany, part of Springer Nature.	en
utb.faculty	University Institute
utb.faculty	Faculty of Technology
dc.identifier.uri	http://hdl.handle.net/10563/1007958
utb.identifier.obdid	43878239
utb.identifier.scopus	2-s2.0-85041552356
utb.identifier.wok	000431664900008
utb.identifier.coden	CJPSE
utb.source	j-scopus
dc.date.accessioned	2018-07-27T08:47:35Z
dc.date.available	2018-07-27T08:47:35Z
dc.description.sponsorship	LO1504, NPU, Northwestern Polytechnical University; MŠMT, Ministerstvo Školství, Mládeže a Tělovýchovy; 17-26808S
dc.description.sponsorship	Grant Agency CR [17-26808S]; Ministry of Education, Youth and Sports of the Czech Republic-Programme NPU I [LO1504]
utb.ou	Centre of Polymer Systems
utb.contributor.internalauthor	Polášková, Martina
utb.contributor.internalauthor	Šuly, Pavol
utb.fulltext.affiliation	Petra Peer a* , Martina Polaskova b, c , and Pavol Suly b a Institute of Hydrodynamics of the Czech Academy of Sciences, Pod Patankou 5, 166 12 Prague 6, Czech Republic b Centre of Polymer Systems, Tomas Bata University in Zlín, trida Tomase Bati 5678,760 01 Zlín, Czech Republic c Department of Polymer Engineering, Faculty of Technology, Tomas Bata University in Zlín, Vavreckova 275, 760 01 Zlín, Czech Republic * Corresponding author: E-mail peer@ih.cas.cz
utb.fulltext.dates	Received August 28, 2017 Accepted October 24, 2017 Published online February 6, 2018
utb.fulltext.references	1 Vanangamudi, A.; Hamzah, S.; Singh, G. Synthesis of hybrid hydrophobic composite air filtration membranes for antibacterial activity and chemical detoxification with high particulate filtration efficiency (PFE). Chem. Eng. J. 2015, 260, 801−808. 2 Khajavi, R.; Abbasipour, M.; Bahador, A. Electrospun biodegradable nanofibers scaffolds for bone tissue engineering. J. Appl. Polym. Sci. 2016, 133(3), 42883. 3 Capulli, A. K.; MacQueen, L. A.; Sheehy, S. P.; Parker, K. K. Fibrous scaffolds for building hearts and heart parts. Adv. Drug Deliv. Rev. 2016, 96, 83−102. 4 Sas, I.; Gorga, R. E.; Joines, J. A.; Thoney, K. A. Literature review on superhydrophobic self-cleaning surfaces produced by electrospinning. J. Polym. Sci., Part B: Polym. Phys. 2012, 50(12), 824−845. 5 Ramakrishna, S.; Fujihara, K.; Teo, W. E.; Lim, T. C.; Ma, Z. "An introduction to electrospinning and nanofibers", World Scientific Publishing Co. Pte. Ltd., Singapore, 2005, p. 90 6 Deitzel, J.; Kleinmeyer, J.; Harris, D.; Tan, N. C. B. The effect of processing variables on the morphology of electrospun nanofibers and textiles. Polymer 2001, 42(1), 261−272. 7 Son, W. K.; Youk, J. H.; Lee, T. S.; Park, W. H. The effects of solution properties and polyelectrolyte on electrospinning of ultrafine poly(ethylene oxide) fibers. Polymer 2004, 45(9), 2959−2966. 8 Han, W.; Nurwaha, D.; Li, C.; Wang, X. Free surface electrospun fibers: the combined effect of processing parameters. Polym. Eng. Sci. 2014, 54(1), 189−197. 9 Basu, S.; Gogoi, N.; Sharma, S.; Jassal, M.; Agrawal, A. K. Role of elasticity in control of diameter of electrospun PAN nanofibers. Fib. Polym. 2013, 14(6), 950−956. 10 Gupta, D.; Jassal, M.; Agrawal, A. K. Electrospinning of poly(vinyl alcohol)-based boger fluids to understand the role of elasticity on morphology of nanofibers. Ind. Eng. Chem. Res. 2015, 54(5), 1547−1554. 11 Dufficy, M. K.; Geiger, M. T.; Bonino, C. A.; Khan, S. A. Electrospun ultrafine fiber composites containing fumed silica: from solution rheology to materials with tunable wetting. Langmuir 2015, 31(45), 12455−12463. 12 Yadav, G. D.; Yadav, A. R. Atom economical Michael addition of indole with methyl vinyl ketone over novel solid acid catalyst sulfated zirconia on silica tubes. Microporous and Mesoporous Mater. 2014, 195, 180−190. 13 Xu, H.; Li, H.; Chang, J. Controlled drug release from a polymer matrix by patterned electrospun nanofibers with controllable hydrophobicity. J. Mater. Chem. B 2013, 1(33), 4182−4188. 14 Chen, L. J.; Liao, J. D.; Lin, S. J.; Chuang, Y. J.; Fu, Y. S. Synthesis and characterization of PVB/silica nanofibers by electrospinning process. Polymer 2009, 50(15), 3516−3521. 15 Fong, H.; Chun, I.; Reneker, D. H. Beaded nanofibers formed during electrospinning. Polymer 1999, 40(16), 4585−4592. 16 Yalcinkaya, F. Experimental study on electrospun polyvinyl butyral nanofibers using a non-solvent system. Fib. Polym. 2015, 16(12), 2544−2551. 17 Cassagnau, P. Melt rheology of organoclay and fumed silica nanocomposites. Polymer 2008, 49(9), 2183−2196. 18 Shenoy, S. L.; Bates, W. D.; Frisch, H. L; Wnek, G. E. Role of chain entanglements on fiber formation during electrospinning of polymer solutions: good solvent, non-specific polymer-polymer interaction limit. Polymer 2005, 46(10), 3372−3384. 19 Yu, J. H.; Fridrikh, S. V.; Rutledge, G. C. The role of elasticity in the formation of electrospun fibers. Polymer 2006, 47(13), 4789−4797. 20 Regev, O.; Vandebril, S.; Zussman, E.; Clasen, C. The role of interfacial viscoelasticity in the stabilization of an electrospun jet. Polymer 2010, 51(12), 2611−2620. 21 Ehrenstein, G. W.; Riedel, G.; Trawiel, P. "Thermal analysis of plastic: theory and practice", Hanser Publishers, Munich, 2004, p. 368
utb.fulltext.sponsorship	The author (P.P.) wishes to acknowledge the Grant Agency CR for the financial support of Grant Project (No. 17-26808S). The authors (M.P. and P.S.) thank the support of the Ministry of Education, Youth and Sports of the Czech Republic—Programme NPU I (No. LO1504).
utb.wos.affiliation	[Peer, Petra] Czech Acad Sci, Inst Hydrodynam, Patankou 5, Prague 16612 6, Czech Republic; [Polaskova, Martina; Suly, Pavol] Tomas Bata Univ Zlin, Ctr Polymer Syst, Trida Tomase Bati 5678, Zlin 76001, Czech Republic; [Polaskova, Martina] Tomas Bata Univ Zlin, Fac Technol, Dept Polymer Engn, Vavreckova 275, Zlin 76001, Czech Republic
utb.scopus.affiliation	Institute of Hydrodynamics of the Czech Academy of Sciences, Pod Patankou 5, Prague 6, Czech Republic; Centre of Polymer Systems, Tomas Bata University in Zlín, trida Tomase Bati 5678, Zlín, Czech Republic; Department of Polymer Engineering, Faculty of Technology, Tomas Bata University in Zlín, Vavreckova 275, Zlín, Czech Republic
utb.fulltext.projects	17-26808S
utb.fulltext.projects	LO1504