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Development of a catalytic model system using nitrous oxide

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dc.title Development of a catalytic model system using nitrous oxide en
dc.contributor.author Beltrán-Prieto, Juan Carlos
dc.contributor.author Kolomazník, Karel
dc.relation.ispartof WSEAS Transactions on Environment and Development
dc.identifier.issn 1790-5079 OCLC, Ulrich, Sherpa/RoMEO, JCR
dc.date.issued 2018
utb.relation.volume 14
dc.citation.spage 256
dc.citation.epage 262
dc.type article
dc.language.iso en
dc.publisher World Scientific and Engineering Academy and Society
dc.relation.uri http://www.wseas.org/multimedia/journals/environment/2018/a515915-014.php
dc.subject 1,2,3 propanotriol en
dc.subject Control en
dc.subject Dihydroxypropanal en
dc.subject Mathematical model en
dc.subject Nitrous oxide en
dc.subject Oxidation en
dc.description.abstract Currently, special attention is paid to partial oxidation of several sugar alcohols because it generates oxidation intermediate products with high utility value. In the present paper, we study the modelling of oxidation reaction of 1,2,3 propanotriol using an oxidizing agent in low concentrations. A major problem of such oxidation system is its low reactivity and high oxidation reactivity of products, As a result, the yield to a specific compound (i.e. dihydroxypropanal) depends on the ratio of rate constants of the consecutive reactions and also on the initial concentration of oxidizing agent. In this case, as the input value for the model calculations we chose a ratio of values of the specified rate constants and initial concentrations of nitrous oxide and 1,2,3-propanotriol. Accordingly, an experimental setup was proposed to follow the variation of temperature of the reaction blend after gradual addition of ammonium nitrate to a solution of 1,2,3 propanotriol, which can provide insights for the control of the chemical reactor. © 2018, World Scientific and Engineering Academy and Society. All Rights Reserved. en
utb.faculty Faculty of Applied Informatics
dc.identifier.uri http://hdl.handle.net/10563/1007887
utb.identifier.scopus 2-s2.0-85045054401
utb.source j-scopus
dc.date.accessioned 2018-04-23T15:01:50Z
dc.date.available 2018-04-23T15:01:50Z
dc.description.sponsorship LO1303, MŠMT, Ministerstvo Školství, Mládeže a Tělovýchovy
utb.contributor.internalauthor Beltrán-Prieto, Juan Carlos
utb.contributor.internalauthor Kolomazník, Karel
utb.fulltext.affiliation JUAN CARLOS BELTRAN-PRIETO, KAREL KOLOMAZNIK Faculty of Applied Informatics Tomas Bata University in Zlín Nám. T. G. Masaryka 5555, 760 01 Zlín CZECH REPUBLIC prieto@fai.utb.cz
utb.fulltext.dates -
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utb.fulltext.sponsorship This work was supported by the Ministry of Education, Youth and Sports of the Czech Republic within the National Sustainability Programme project No. LO1303 (MSMT7778/2014).
utb.scopus.affiliation Faculty of Applied Informatics, Tomas Bata University in Zlín, Nám. T. G. Masaryka 5555, Zlín, Czech Republic
utb.fulltext.projects LO1303 (MSMT7778/2014)
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