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Microporous conjugated polymers via homopolymerization of 2,5-diethynylthiophene

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dc.title Microporous conjugated polymers via homopolymerization of 2,5-diethynylthiophene en
dc.contributor.author Bondarev, Dmitrij
dc.contributor.author Sivkova, Radoslava
dc.contributor.author Šuly, Pavol
dc.contributor.author Polášková, Martina
dc.contributor.author Krejčí, Ondřej
dc.contributor.author Křikavová, Radka
dc.contributor.author Trávníček, Zdeněk
dc.contributor.author Zukal, Arnošt
dc.contributor.author Kubů, Martin
dc.contributor.author Sedláček, Jan
dc.relation.ispartof European Polymer Journal
dc.identifier.issn 0014-3057 OCLC, Ulrich, Sherpa/RoMEO, JCR
dc.date.issued 2017
utb.relation.volume 92
dc.citation.spage 213
dc.citation.epage 219
dc.type article
dc.language.iso en
dc.publisher Elsevier Ltd.
dc.identifier.doi 10.1016/j.eurpolymj.2017.04.042
dc.relation.uri https://www.sciencedirect.com/science/article/pii/S0014305717300162
dc.subject Thiophene en
dc.subject Microporous en
dc.subject Catalysis en
dc.subject Polymerization en
dc.subject Conjugated polymer en
dc.subject Adsorption en
dc.description.abstract Homopolymerizations of 2,5-diethynylthiophene into conjugated microporous polymers by (i) chain-growth polymerization and (ii) polycyclotrimerization are described. Both methods provide nearly quantitative yields of thiophene-rich (7.6 mmol thiophene rings/g) networks with specific surface area up to 839 m2/g. The thiophene units enhance the affinity of the networks to CO2 and red-shift the UV/vis and fluorescence absorption and emission bands of the networks, respectively. © 2017 Elsevier Ltd en
utb.faculty University Institute
dc.identifier.uri http://hdl.handle.net/10563/1007349
utb.identifier.obdid 43876694
utb.identifier.scopus 2-s2.0-85019182165
utb.identifier.wok 000404315600020
utb.identifier.coden EUPJA
utb.source j-scopus
dc.date.accessioned 2017-09-08T12:14:43Z
dc.date.available 2017-09-08T12:14:43Z
dc.description.sponsorship 15-09637S, GACR, Grantová Agentura České Republiky
dc.description.sponsorship Czech Science Foundation [15-09637S]; Ministry of Education, Youth and Sports [NPU I (LO1504)]; Slovak Research and Development Agency APVV [APVV-15-0545]
utb.ou Centre of Polymer Systems
utb.contributor.internalauthor Šuly, Pavol
utb.contributor.internalauthor Polášková, Martina
utb.contributor.internalauthor Krejčí, Ondřej
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